Coordination of C60 to penta- and hexaruthenium cluster frames

Kwangyeol Lee, Hsiu Fu Hsu, John R. Shapley

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Abstract

In refluxing chlorobenzene C60 reacts with Ru5C(CO)15 or with Ru6C(CO)17 to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, facebonded derivatives Ru5C(CO)11(PPh3)(μ3222-C60) (1) and Ru6C(CO)12(dppm)(μ3222-C60) (2).

Original languageEnglish
Pages (from-to)3876-3877
Number of pages2
JournalOrganometallics
Volume16
Issue number18
Publication statusPublished - 1997 Sep 2
Externally publishedYes

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ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Lee, K., Hsu, H. F., & Shapley, J. R. (1997). Coordination of C60 to penta- and hexaruthenium cluster frames. Organometallics, 16(18), 3876-3877.