Coordination of C60 to penta- and hexaruthenium cluster frames

Kwangyeol Lee; Hsiu Fu Hsu; John R. Shapley

doi:10.1021/om970265v

Coordination of C₆₀ to penta- and hexaruthenium cluster frames

Kwangyeol Lee, Hsiu Fu Hsu, John R. Shapley

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59 Citations (Scopus)

Abstract

In refluxing chlorobenzene C₆₀ reacts with Ru₅C(CO)₁₅ or with Ru₆C(CO)₁₇ to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, facebonded derivatives Ru₅C(CO)₁₁(PPh₃)(μ₃-η ²:η²:η²-C₆₀) (1) and Ru₆C(CO)₁₂(dppm)(μ₃-η ²:η²:η²-C₆₀) (2).

Original language	English
Pages (from-to)	3876-3877
Number of pages	2
Journal	Organometallics
Volume	16
Issue number	18
DOIs	https://doi.org/10.1021/om970265v
Publication status	Published - 1997 Sept 2
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Coordination of C60 to penta- and hexaruthenium cluster frames",

abstract = "In refluxing chlorobenzene C60 reacts with Ru5C(CO)15 or with Ru6C(CO)17 to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, facebonded derivatives Ru5C(CO)11(PPh3)(μ3-η 2:η2:η2-C60) (1) and Ru6C(CO)12(dppm)(μ3-η 2:η2:η2-C60) (2).",

author = "Kwangyeol Lee and Hsu, {Hsiu Fu} and Shapley, {John R.}",

year = "1997",

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AU - Lee, Kwangyeol

AU - Hsu, Hsiu Fu

AU - Shapley, John R.

PY - 1997/9/2

Y1 - 1997/9/2

N2 - In refluxing chlorobenzene C60 reacts with Ru5C(CO)15 or with Ru6C(CO)17 to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, facebonded derivatives Ru5C(CO)11(PPh3)(μ3-η 2:η2:η2-C60) (1) and Ru6C(CO)12(dppm)(μ3-η 2:η2:η2-C60) (2).

AB - In refluxing chlorobenzene C60 reacts with Ru5C(CO)15 or with Ru6C(CO)17 to form new complexes, which are isolated following treatment with tertiary phosphines to give the structurally characterized, facebonded derivatives Ru5C(CO)11(PPh3)(μ3-η 2:η2:η2-C60) (1) and Ru6C(CO)12(dppm)(μ3-η 2:η2:η2-C60) (2).

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Coordination of C₆₀ to penta- and hexaruthenium cluster frames

Abstract

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