Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter

Young Kwan Park, Beom Choi Sang, Hyunuk Kim, Kimoon Kim, Byoung Ho Won, Kihang Choi, Jung Sik Choi, Wha Seung Ahn, Nayoun Won, Sungjee Kim, Hyun Jung Dong, Seung Hoon Choi, Ghyung Hwa Kim, Sun Shin Cha, Ho Jhon Young, Kuk Yang Jin, Jaheon Kim

Research output: Contribution to journalArticle

269 Citations (Scopus)

Abstract

(Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies.

Original languageEnglish
Pages (from-to)8230-8233
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number43
DOIs
Publication statusPublished - 2007

Keywords

  • Adsorption
  • Luminescence
  • Mesoporous materials
  • Metal-organic frameworks
  • Terbium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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    Park, Y. K., Sang, B. C., Kim, H., Kim, K., Won, B. H., Choi, K., Choi, J. S., Ahn, W. S., Won, N., Kim, S., Dong, H. J., Choi, S. H., Kim, G. H., Cha, S. S., Young, H. J., Jin, K. Y., & Kim, J. (2007). Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter. Angewandte Chemie - International Edition, 46(43), 8230-8233. https://doi.org/10.1002/anie.200702324