Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter

Young Kwan Park, Beom Choi Sang, Hyunuk Kim, Kimoon Kim, Byoung Ho Won, Kihang Choi, Jung Sik Choi, Wha Seung Ahn, Nayoun Won, Sungjee Kim, Hyun Jung Dong, Seung Hoon Choi, Ghyung Hwa Kim, Sun Shin Cha, Ho Jhon Young, Kuk Yang Jin, Jaheon Kim

Research output: Contribution to journalArticle

260 Citations (Scopus)

Abstract

(Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies.

Original languageEnglish
Pages (from-to)8230-8233
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number43
DOIs
Publication statusPublished - 2007 Nov 19

Fingerprint

Crystal structure
Gases
Metals
Sorption
Luminescence
Ligands
Ions
Molecules
ferrocene

Keywords

  • Adsorption
  • Luminescence
  • Mesoporous materials
  • Metal-organic frameworks
  • Terbium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter. / Park, Young Kwan; Sang, Beom Choi; Kim, Hyunuk; Kim, Kimoon; Won, Byoung Ho; Choi, Kihang; Choi, Jung Sik; Ahn, Wha Seung; Won, Nayoun; Kim, Sungjee; Dong, Hyun Jung; Choi, Seung Hoon; Kim, Ghyung Hwa; Cha, Sun Shin; Young, Ho Jhon; Jin, Kuk Yang; Kim, Jaheon.

In: Angewandte Chemie - International Edition, Vol. 46, No. 43, 19.11.2007, p. 8230-8233.

Research output: Contribution to journalArticle

Park, YK, Sang, BC, Kim, H, Kim, K, Won, BH, Choi, K, Choi, JS, Ahn, WS, Won, N, Kim, S, Dong, HJ, Choi, SH, Kim, GH, Cha, SS, Young, HJ, Jin, KY & Kim, J 2007, 'Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter', Angewandte Chemie - International Edition, vol. 46, no. 43, pp. 8230-8233. https://doi.org/10.1002/anie.200702324
Park, Young Kwan ; Sang, Beom Choi ; Kim, Hyunuk ; Kim, Kimoon ; Won, Byoung Ho ; Choi, Kihang ; Choi, Jung Sik ; Ahn, Wha Seung ; Won, Nayoun ; Kim, Sungjee ; Dong, Hyun Jung ; Choi, Seung Hoon ; Kim, Ghyung Hwa ; Cha, Sun Shin ; Young, Ho Jhon ; Jin, Kuk Yang ; Kim, Jaheon. / Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 43. pp. 8230-8233.
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