Cs-promoted Ni/Fe catalyst as a Cr-free, high temperature shift catalyst for steam methane reformate without additional supply of steam

Joon Yeob Lee; Dae Won Lee; Myung Suk Lee; Kwan Young Lee

doi:10.1016/j.catcom.2011.08.010

Cs-promoted Ni/Fe catalyst as a Cr-free, high temperature shift catalyst for steam methane reformate without additional supply of steam

Joon Yeob Lee, Dae Won Lee, Myung Suk Lee, Kwan Young Lee

Department of Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The goal of this study was to investigate the Cs-promoted Ni/Fe catalysts for high temperature shift reaction. The performance of all the catalysts was evaluated at 400 °C and 75,000 ml/g_cat h under the reactant composition: 56.7% H₂, 10% CO, 26.7% H₂O, and 6.7% CO ₂, assuming gas production from the steam methane reformer at a H₂O/CH₄ ratio = 3 with 100% CH₄ conversion and with no extra steam added for the protection of the catalyst. The Cs/Ni/Fe (Ni:Fe = 34:66; weight ratio) catalysts of 3.9-6.0 Cs wt.% showed excellent CO removal activities and suppressed the progress of methanation effectively. This performance was related to the increment of amount in weakly basic sites through Cs promotion.

Original language	English
Pages (from-to)	37-40
Number of pages	4
Journal	Catalysis Communications
Volume	15
Issue number	1
DOIs	https://doi.org/10.1016/j.catcom.2011.08.010
Publication status	Published - 2011 Nov 15

Keywords

Alkali-metal promoted catalyst
High temperature shift
Methanation
Ni/Fe
Water gas shift reaction

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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10.1016/j.catcom.2011.08.010

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title = "Cs-promoted Ni/Fe catalyst as a Cr-free, high temperature shift catalyst for steam methane reformate without additional supply of steam",

abstract = "The goal of this study was to investigate the Cs-promoted Ni/Fe catalysts for high temperature shift reaction. The performance of all the catalysts was evaluated at 400 °C and 75,000 ml/gcat h under the reactant composition: 56.7% H2, 10% CO, 26.7% H2O, and 6.7% CO 2, assuming gas production from the steam methane reformer at a H2O/CH4 ratio = 3 with 100% CH4 conversion and with no extra steam added for the protection of the catalyst. The Cs/Ni/Fe (Ni:Fe = 34:66; weight ratio) catalysts of 3.9-6.0 Cs wt.% showed excellent CO removal activities and suppressed the progress of methanation effectively. This performance was related to the increment of amount in weakly basic sites through Cs promotion.",

keywords = "Alkali-metal promoted catalyst, High temperature shift, Methanation, Ni/Fe, Water gas shift reaction",

author = "Lee, {Joon Yeob} and Lee, {Dae Won} and Lee, {Myung Suk} and Lee, {Kwan Young}",

note = "Funding Information: The authors gratefully acknowledgement the financial support provided by the Seoul Development Institute (SDI) through the Seoul R&BD program ( 10575 ) and by the Korea Institute of Science and Technology (KIST) through the Institutional Program ( 2E22143 ). Funding Information: Dr. Dae-Won Lee was supported by Korea University Grant. ",

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doi = "10.1016/j.catcom.2011.08.010",

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AU - Lee, Dae Won

AU - Lee, Myung Suk

AU - Lee, Kwan Young

N1 - Funding Information: The authors gratefully acknowledgement the financial support provided by the Seoul Development Institute (SDI) through the Seoul R&BD program ( 10575 ) and by the Korea Institute of Science and Technology (KIST) through the Institutional Program ( 2E22143 ). Funding Information: Dr. Dae-Won Lee was supported by Korea University Grant.

PY - 2011/11/15

Y1 - 2011/11/15

N2 - The goal of this study was to investigate the Cs-promoted Ni/Fe catalysts for high temperature shift reaction. The performance of all the catalysts was evaluated at 400 °C and 75,000 ml/gcat h under the reactant composition: 56.7% H2, 10% CO, 26.7% H2O, and 6.7% CO 2, assuming gas production from the steam methane reformer at a H2O/CH4 ratio = 3 with 100% CH4 conversion and with no extra steam added for the protection of the catalyst. The Cs/Ni/Fe (Ni:Fe = 34:66; weight ratio) catalysts of 3.9-6.0 Cs wt.% showed excellent CO removal activities and suppressed the progress of methanation effectively. This performance was related to the increment of amount in weakly basic sites through Cs promotion.

AB - The goal of this study was to investigate the Cs-promoted Ni/Fe catalysts for high temperature shift reaction. The performance of all the catalysts was evaluated at 400 °C and 75,000 ml/gcat h under the reactant composition: 56.7% H2, 10% CO, 26.7% H2O, and 6.7% CO 2, assuming gas production from the steam methane reformer at a H2O/CH4 ratio = 3 with 100% CH4 conversion and with no extra steam added for the protection of the catalyst. The Cs/Ni/Fe (Ni:Fe = 34:66; weight ratio) catalysts of 3.9-6.0 Cs wt.% showed excellent CO removal activities and suppressed the progress of methanation effectively. This performance was related to the increment of amount in weakly basic sites through Cs promotion.

KW - Alkali-metal promoted catalyst

KW - High temperature shift

KW - Methanation

KW - Ni/Fe

KW - Water gas shift reaction

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JF - Catalysis Communications

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Cs-promoted Ni/Fe catalyst as a Cr-free, high temperature shift catalyst for steam methane reformate without additional supply of steam

Abstract

Keywords

ASJC Scopus subject areas

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