Cu-Ni nanoalloy phase diagram - Prediction and experiment

Jiri Sopousek; Jan Vrestal; Jiri Pinkas; Pavel Broz; Jiri Bursik; Ales Styskalik; David Skoda; Ondrej Zobac; Joonho Lee

doi:10.1016/j.calphad.2013.11.004

Cu-Ni nanoalloy phase diagram - Prediction and experiment

Jiri Sopousek, Jan Vrestal, Jiri Pinkas, Pavel Broz, Jiri Bursik, Ales Styskalik, David Skoda, Ondrej Zobac, Joonho Lee

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

71 Citations (Scopus)

Abstract

The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.

Original language	English
Pages (from-to)	33-39
Number of pages	7
Journal	Calphad: Computer Coupling of Phase Diagrams and Thermochemistry
Volume	45
DOIs	https://doi.org/10.1016/j.calphad.2013.11.004
Publication status	Published - 2014 Jun

Keywords

Characterization
Nanoalloy
Phase diagram
Surface energy
Thermodynamic modeling

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Computer Science Applications

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10.1016/j.calphad.2013.11.004

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title = "Cu-Ni nanoalloy phase diagram - Prediction and experiment",

abstract = "The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.",

keywords = "Characterization, Nanoalloy, Phase diagram, Surface energy, Thermodynamic modeling",

author = "Jiri Sopousek and Jan Vrestal and Jiri Pinkas and Pavel Broz and Jiri Bursik and Ales Styskalik and David Skoda and Ondrej Zobac and Joonho Lee",

note = "Funding Information: Financial support of the Ministry of Education of the Czech Republic under the project LD 11046 (within COST MP0903 Action), RVO: 68081723 , and CEITEC-MU CZ.1.05/1.1.00/02.0068 are gratefully acknowledged. ",

year = "2014",

month = jun,

doi = "10.1016/j.calphad.2013.11.004",

language = "English",

volume = "45",

pages = "33--39",

journal = "Calphad: Computer Coupling of Phase Diagrams and Thermochemistry",

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T1 - Cu-Ni nanoalloy phase diagram - Prediction and experiment

AU - Sopousek, Jiri

AU - Vrestal, Jan

AU - Pinkas, Jiri

AU - Broz, Pavel

AU - Bursik, Jiri

AU - Styskalik, Ales

AU - Skoda, David

AU - Zobac, Ondrej

AU - Lee, Joonho

N1 - Funding Information: Financial support of the Ministry of Education of the Czech Republic under the project LD 11046 (within COST MP0903 Action), RVO: 68081723 , and CEITEC-MU CZ.1.05/1.1.00/02.0068 are gratefully acknowledged.

PY - 2014/6

Y1 - 2014/6

N2 - The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.

AB - The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.

KW - Characterization

KW - Nanoalloy

KW - Phase diagram

KW - Surface energy

KW - Thermodynamic modeling

UR - http://www.scopus.com/inward/record.url?scp=84890810303&partnerID=8YFLogxK

U2 - 10.1016/j.calphad.2013.11.004

DO - 10.1016/j.calphad.2013.11.004

M3 - Article

AN - SCOPUS:84890810303

SN - 0364-5916

VL - 45

SP - 33

EP - 39

JO - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

JF - Calphad: Computer Coupling of Phase Diagrams and Thermochemistry

ER -

Cu-Ni nanoalloy phase diagram - Prediction and experiment

Abstract

Keywords

ASJC Scopus subject areas

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