Abstract
The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.
| Original language | English |
|---|---|
| Pages (from-to) | 713-720 |
| Number of pages | 8 |
| Journal | Journal of Polymer Science, Part A: Polymer Chemistry |
| Volume | 37 |
| Issue number | 6 |
| Publication status | Published - 1999 Mar 15 |
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Keywords
- Biphenyl epoxy resin
- Concentration of catalyst
- Cure kinetics
- Phenol novolac resin
- Triphenylphosphine
ASJC Scopus subject areas
- Materials Chemistry
- Polymers and Plastics
Cite this
Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst. / Han, Seung; Yoon, Ho Gyu; Suh, Kwang Suck; Kim, Whan Gun; Moon, Tak Jin.
In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 37, No. 6, 15.03.1999, p. 713-720.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst
AU - Han, Seung
AU - Yoon, Ho Gyu
AU - Suh, Kwang Suck
AU - Kim, Whan Gun
AU - Moon, Tak Jin
PY - 1999/3/15
Y1 - 1999/3/15
N2 - The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.
AB - The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.
KW - Biphenyl epoxy resin
KW - Concentration of catalyst
KW - Cure kinetics
KW - Phenol novolac resin
KW - Triphenylphosphine
UR - http://www.scopus.com/inward/record.url?scp=0033097886&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033097886&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0033097886
VL - 37
SP - 713
EP - 720
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
SN - 0887-624X
IS - 6
ER -