Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst

Seung Han; Ho Gyu Yoon; Kwang S. Suh; Whan Gun Kim; Tak Jin Moon

doi:10.1002/(SICI)1099-0518(19990315)37:6<713::AID-POLA6>3.0.CO;2-I

Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst

Seung Han, Ho Gyu Yoon, Kwang S. Suh, Whan Gun Kim, Tak Jin Moon

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.

Original language	English
Pages (from-to)	713-720
Number of pages	8
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	37
Issue number	6
DOIs	https://doi.org/10.1002/(SICI)1099-0518(19990315)37:6<713::AID-POLA6>3.0.CO;2-I
Publication status	Published - 1999 Mar 15

Keywords

Biphenyl epoxy resin
Concentration of catalyst
Cure kinetics
Phenol novolac resin
Triphenylphosphine

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

Access to Document

10.1002/(SICI)1099-0518(19990315)37:6<713::AID-POLA6>3.0.CO;2-I

Cite this

@article{a3e84014fb6d4866a4552d34ad0980f6,

title = "Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst",

abstract = "The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.",

keywords = "Biphenyl epoxy resin, Concentration of catalyst, Cure kinetics, Phenol novolac resin, Triphenylphosphine",

author = "Seung Han and Yoon, {Ho Gyu} and Suh, {Kwang S.} and Kim, {Whan Gun} and Moon, {Tak Jin}",

year = "1999",

month = mar,

day = "15",

doi = "10.1002/(SICI)1099-0518(19990315)37:6<713::AID-POLA6>3.0.CO;2-I",

language = "English",

volume = "37",

pages = "713--720",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley and Sons Inc.",

number = "6",

}

TY - JOUR

T1 - Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst

AU - Han, Seung

AU - Yoon, Ho Gyu

AU - Suh, Kwang S.

AU - Kim, Whan Gun

AU - Moon, Tak Jin

PY - 1999/3/15

Y1 - 1999/3/15

N2 - The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.

AB - The effects of the concentration of triphenylphosphine as a catalyst on the cure reaction of the biphenyl epoxy/phenol novolac resin system were studied. The kinetic study was carried out by means of the analysis of isothermal experiments using a differential scanning calorimeter. All kinetic parameters including the reaction orders, activation energy and kinetic rate constants were evaluated. To describe the cure reaction with the catalyst concentration, the normalized kinetic model was developed. The suggested kinetic model with a diffusion term was successfully able to describe and predict the cure reaction of epoxy resin compositions as functions of the catalyst content and temperature.

KW - Biphenyl epoxy resin

KW - Concentration of catalyst

KW - Cure kinetics

KW - Phenol novolac resin

KW - Triphenylphosphine

UR - http://www.scopus.com/inward/record.url?scp=0033097886&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033097886&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1099-0518(19990315)37:6<713::AID-POLA6>3.0.CO;2-I

DO - 10.1002/(SICI)1099-0518(19990315)37:6<713::AID-POLA6>3.0.CO;2-I

M3 - Article

AN - SCOPUS:0033097886

VL - 37

SP - 713

EP - 720

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 6

ER -

Cure Kinetics of Biphenyl Epoxy-Phenol Novolac Resin System Using Triphenylphosphine as Catalyst

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this