@article{d8f352e8e1744abba492de9a59db6477,
title = "Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets",
abstract = "Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail.",
author = "Lim, {Kwang Soo} and Baldov{\'i}, {Jos{\'e} J.} and Jiang, {Shang Da} and Koo, {Bong Ho} and Kang, {Dong Won} and Lee, {Woo Ram} and Koh, {Eui Kwan} and Alejandro Gaita-Ari{\~n}o and Eugenio Coronado and Michael Slota and Lapo Bogani and Hong, {Chang Seop}",
note = "Funding Information: We are thankful for financial support from the Korean Basic Science Research Program (NRF-2015R1A2A1A10055658), an KCRC grant (Grant NRF-2012-0008901), the Korean Priority Research Centers Program (NRF2010-0020209), EU (ERCCoG-647301 DECRESIM, ERC-StG-338258 OptoQMol, and COST Action 15128 MOLSPIN), the Spanish MINECO (Grant MAT2014-56143-R, CTQ2014-52758-P and Excellence Unit Mari?a de Maeztu MDM-2015-0538), and the Generalitat Valenciana (Prometeo Programme of excellence). A.G.-A. acknowledges funding by the MINECO (Ramo?n y Cajal contract).",
year = "2017",
month = may,
day = "1",
doi = "10.1021/acs.inorgchem.6b03118",
language = "English",
volume = "56",
pages = "4911--4917",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "9",
}