Cu2+ Ion-induced self-assembly of pyrenylquinoline with a pyrenyl excimer formation

Hyo Sung Jung; Mirae Park; Do Young Han; Eunmi Kim; Chewook Lee; Sihyun Ham; Jong Seung Kim

doi:10.1021/ol901221q

Cu²⁺ Ion-induced self-assembly of pyrenylquinoline with a pyrenyl excimer formation

Hyo Sung Jung, Mirae Park, Do Young Han, Eunmi Kim, Chewook Lee, Sihyun Ham, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

155 Citations (Scopus)

Abstract

Synthesis of a novel pyrene derivative sensor (1) and its intermolecular binding pattern to Cu²⁺ in CH₃CN were investigated. Upon Cu²⁺ binding, the sensor exhibited a strong static excimer emission at 460 nm, along with a weak monomer emission at 388 nm. The excimer emission intensity induced by the Cu²⁺ ion declined as the spacer length between the pyrene and quinolinylamide unit increased. The Cu²⁺ ion-induced self-assembled pyrenyl excimer formation is rationalized by fluorescence experiments and theoretical DFT calculations.

Original language	English
Pages (from-to)	3378-3381
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	15
DOIs	https://doi.org/10.1021/ol901221q
Publication status	Published - 2009 Aug 6

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Cu2+ Ion-induced self-assembly of pyrenylquinoline with a pyrenyl excimer formation",

abstract = "Synthesis of a novel pyrene derivative sensor (1) and its intermolecular binding pattern to Cu2+ in CH3CN were investigated. Upon Cu2+ binding, the sensor exhibited a strong static excimer emission at 460 nm, along with a weak monomer emission at 388 nm. The excimer emission intensity induced by the Cu2+ ion declined as the spacer length between the pyrene and quinolinylamide unit increased. The Cu2+ ion-induced self-assembled pyrenyl excimer formation is rationalized by fluorescence experiments and theoretical DFT calculations.",

author = "Jung, {Hyo Sung} and Mirae Park and Han, {Do Young} and Eunmi Kim and Chewook Lee and Sihyun Ham and Kim, {Jong Seung}",

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journal = "Organic Letters",

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T1 - Cu2+ Ion-induced self-assembly of pyrenylquinoline with a pyrenyl excimer formation

AU - Jung, Hyo Sung

AU - Park, Mirae

AU - Han, Do Young

AU - Kim, Eunmi

AU - Lee, Chewook

AU - Ham, Sihyun

AU - Kim, Jong Seung

PY - 2009/8/6

Y1 - 2009/8/6

N2 - Synthesis of a novel pyrene derivative sensor (1) and its intermolecular binding pattern to Cu2+ in CH3CN were investigated. Upon Cu2+ binding, the sensor exhibited a strong static excimer emission at 460 nm, along with a weak monomer emission at 388 nm. The excimer emission intensity induced by the Cu2+ ion declined as the spacer length between the pyrene and quinolinylamide unit increased. The Cu2+ ion-induced self-assembled pyrenyl excimer formation is rationalized by fluorescence experiments and theoretical DFT calculations.

AB - Synthesis of a novel pyrene derivative sensor (1) and its intermolecular binding pattern to Cu2+ in CH3CN were investigated. Upon Cu2+ binding, the sensor exhibited a strong static excimer emission at 460 nm, along with a weak monomer emission at 388 nm. The excimer emission intensity induced by the Cu2+ ion declined as the spacer length between the pyrene and quinolinylamide unit increased. The Cu2+ ion-induced self-assembled pyrenyl excimer formation is rationalized by fluorescence experiments and theoretical DFT calculations.

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JF - Organic Letters

SN - 1523-7060

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Cu²⁺ Ion-induced self-assembly of pyrenylquinoline with a pyrenyl excimer formation

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