Cu2+ Ion-induced self-assembly of pyrenylquinoline with a pyrenyl excimer formation

Hyo Sung Jung, Mirae Park, Do Young Han, Eunmi Kim, Chewook Lee, Sihyun Ham, Jong Seung Kim

Research output: Contribution to journalArticle

151 Citations (Scopus)

Abstract

Synthesis of a novel pyrene derivative sensor (1) and its intermolecular binding pattern to Cu2+ in CH3CN were investigated. Upon Cu2+ binding, the sensor exhibited a strong static excimer emission at 460 nm, along with a weak monomer emission at 388 nm. The excimer emission intensity induced by the Cu2+ ion declined as the spacer length between the pyrene and quinolinylamide unit increased. The Cu2+ ion-induced self-assembled pyrenyl excimer formation is rationalized by fluorescence experiments and theoretical DFT calculations.

Original languageEnglish
Pages (from-to)3378-3381
Number of pages4
JournalOrganic Letters
Volume11
Issue number15
DOIs
Publication statusPublished - 2009 Aug 6

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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