Cyanide-bridged W VMn III single-chain magnet based on an octacoordinate [W(CN) 6(phen)] - anion

Jinwuk Lee, Kwangsoo Lim, Junghee Yoon, Daewon Ryu, Bongho Koo, Euikwan Koh, Changseop Hong

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Reaction of unique [W(CN) 6(phen) - with a magnetically anisotropic Mn Schiff base yielded a W V(5d)-Mn III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

Original languageEnglish
Pages (from-to)1012-1017
Number of pages6
JournalScience China Chemistry
Volume55
Issue number6
DOIs
Publication statusPublished - 2012 Jun 1

Keywords

  • crystal structure
  • cyanide
  • manganese
  • single-chain magnet
  • tungsten

ASJC Scopus subject areas

  • Chemistry(all)

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