Cyanide-bridged W(V)-Mn(II) bimetallic double-zigzag chains with a metamagnetic nature

Hee Yoon Jung; Chan Kim Hyoung; Seop Hong Chang

doi:10.1021/ic051415u

Cyanide-bridged W(V)-Mn(II) bimetallic double-zigzag chains with a metamagnetic nature

Hee Yoon Jung, Chan Kim Hyoung, Seop Hong Chang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A cyanide-bridged W-Mn bimetallic compound [W(CN)₆(bpy)] ₂[Mn-(H₂O)₂]·4H₂O (1) (bpy = 2,2′-bipyridine) with a one-dimensional, crossed double-zigzag chain structure was prepared by self-assembling [W(CN)₆(bpy)]^- and Mn²⁺ ions in a 2:1 reaction ratio. The magnetic properties of 1 exhibit a field-induced metamagnetic behavior.

Original language	English
Pages (from-to)	7714-7716
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	22
DOIs	https://doi.org/10.1021/ic051415u
Publication status	Published - 2005 Oct 31

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic051415u

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title = "Cyanide-bridged W(V)-Mn(II) bimetallic double-zigzag chains with a metamagnetic nature",

abstract = "A cyanide-bridged W-Mn bimetallic compound [W(CN)6(bpy)] 2[Mn-(H2O)2]·4H2O (1) (bpy = 2,2′-bipyridine) with a one-dimensional, crossed double-zigzag chain structure was prepared by self-assembling [W(CN)6(bpy)]- and Mn2+ ions in a 2:1 reaction ratio. The magnetic properties of 1 exhibit a field-induced metamagnetic behavior.",

author = "Jung, {Hee Yoon} and Hyoung, {Chan Kim} and Chang, {Seop Hong}",

year = "2005",

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journal = "Inorganic Chemistry",

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AU - Jung, Hee Yoon

AU - Hyoung, Chan Kim

AU - Chang, Seop Hong

PY - 2005/10/31

Y1 - 2005/10/31

N2 - A cyanide-bridged W-Mn bimetallic compound [W(CN)6(bpy)] 2[Mn-(H2O)2]·4H2O (1) (bpy = 2,2′-bipyridine) with a one-dimensional, crossed double-zigzag chain structure was prepared by self-assembling [W(CN)6(bpy)]- and Mn2+ ions in a 2:1 reaction ratio. The magnetic properties of 1 exhibit a field-induced metamagnetic behavior.

AB - A cyanide-bridged W-Mn bimetallic compound [W(CN)6(bpy)] 2[Mn-(H2O)2]·4H2O (1) (bpy = 2,2′-bipyridine) with a one-dimensional, crossed double-zigzag chain structure was prepared by self-assembling [W(CN)6(bpy)]- and Mn2+ ions in a 2:1 reaction ratio. The magnetic properties of 1 exhibit a field-induced metamagnetic behavior.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Cyanide-bridged W(V)-Mn(II) bimetallic double-zigzag chains with a metamagnetic nature

Abstract

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