Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts

Nakcheol Jeong, Dong Hoon Kim, Jun Hun Choi

Research output: Contribution to journalArticle

56 Citations (Scopus)

Abstract

Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.

Original languageEnglish
Pages (from-to)1134-1135
Number of pages2
JournalChemical Communications
Volume10
Issue number9
Publication statusPublished - 2004 May 7

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Ethers
Enantioselectivity
Catalysts
1-pentene-3-one

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts. / Jeong, Nakcheol; Kim, Dong Hoon; Choi, Jun Hun.

In: Chemical Communications, Vol. 10, No. 9, 07.05.2004, p. 1134-1135.

Research output: Contribution to journalArticle

Jeong, Nakcheol ; Kim, Dong Hoon ; Choi, Jun Hun. / Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts. In: Chemical Communications. 2004 ; Vol. 10, No. 9. pp. 1134-1135.
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