Abstract
Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a–c) and propargyl 1-vinylallyl ethers (1d–e), by asymmetric Pauson–Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.
| Original language | English |
|---|---|
| Pages (from-to) | 1134-1135 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Volume | 4 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 2004 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry