Development of a continuous hydrogen generator fueled by ammonia borane for portable fuel cell applications

Yongmin Kim; Yujong Kim; Shinyoung Yeo; Kibeom Kim; Katherine Jung-Eun Koh; Jung Eun Seo; Seock Jae Shin; Dae Ki Choi; Chang Won Yoon; Suk Woo Nam

doi:10.1016/j.jpowsour.2012.11.045

Development of a continuous hydrogen generator fueled by ammonia borane for portable fuel cell applications

Yongmin Kim, Yujong Kim, Shinyoung Yeo, Kibeom Kim, Katherine Jung-Eun Koh, Jung Eun Seo, Seock Jae Shin, Dae Ki Choi, Chang Won Yoon, Suk Woo Nam

GREEN SCHOOL (Graduate School of Energy and Environment)

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Thermally-induced dehydrogenation from a mixture of ammonia borane (AB) and a chemical promoter, tetraethyleneglycol dimethylether (T4EGDE) (AB:T4EGDE = 79:21, wt%) has been demonstrated as an efficient method for hydrogen production at 85-145 °C. We further build on these prior results to create a continuous H₂ generator fueled by solid AB beads. The as-developed H₂ generator releases ca. 2 equiv of hydrogen autothermally during operation by utilizing excess heat produced from AB dehydrogenation without any external heater. A purifying system equipped with acidic filter materials is further utilized to remove gaseous byproducts other than hydrogen. The H ₂ generator shows a rapid H₂-release rate up to 3.3 l(H₂) min^-1 with fast load-following capability. The as-developed H₂ generator is ultimately integrated with a commercial 200 W_e polymer electrolyte membrane fuel cell (PEMFC) to test its capability.

Original language	English
Pages (from-to)	170-178
Number of pages	9
Journal	Journal of Power Sources
Volume	229
DOIs	https://doi.org/10.1016/j.jpowsour.2012.11.045
Publication status	Published - 2013

Keywords

Ammonia borane
Continuous hydrogen generation
Polymer electrolyte membrane fuel cell
Solvent-mediated thermolysis

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jpowsour.2012.11.045

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@article{3c33789ff7c140f1acffb86049f3b7c4,

title = "Development of a continuous hydrogen generator fueled by ammonia borane for portable fuel cell applications",

abstract = "Thermally-induced dehydrogenation from a mixture of ammonia borane (AB) and a chemical promoter, tetraethyleneglycol dimethylether (T4EGDE) (AB:T4EGDE = 79:21, wt%) has been demonstrated as an efficient method for hydrogen production at 85-145 °C. We further build on these prior results to create a continuous H2 generator fueled by solid AB beads. The as-developed H2 generator releases ca. 2 equiv of hydrogen autothermally during operation by utilizing excess heat produced from AB dehydrogenation without any external heater. A purifying system equipped with acidic filter materials is further utilized to remove gaseous byproducts other than hydrogen. The H 2 generator shows a rapid H2-release rate up to 3.3 l(H2) min-1 with fast load-following capability. The as-developed H2 generator is ultimately integrated with a commercial 200 We polymer electrolyte membrane fuel cell (PEMFC) to test its capability.",

keywords = "Ammonia borane, Continuous hydrogen generation, Polymer electrolyte membrane fuel cell, Solvent-mediated thermolysis",

author = "Yongmin Kim and Yujong Kim and Shinyoung Yeo and Kibeom Kim and {Jung-Eun Koh}, Katherine and Seo, {Jung Eun} and Shin, {Seock Jae} and Choi, {Dae Ki} and Yoon, {Chang Won} and Nam, {Suk Woo}",

note = "Funding Information: This research was supported by the Hydrogen Energy R&D Center, one of the 21st Century Frontier R&D Program, funded by the Ministry of Education, Science and Technology of Korea . Part of this work was also supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP) and by the Ministry of Knowledge Economy (MEST) (the New Renewable Energy Program, NO. 20113030040020 ). ",

year = "2013",

doi = "10.1016/j.jpowsour.2012.11.045",

language = "English",

volume = "229",

pages = "170--178",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

}

TY - JOUR

T1 - Development of a continuous hydrogen generator fueled by ammonia borane for portable fuel cell applications

AU - Kim, Yongmin

AU - Kim, Yujong

AU - Yeo, Shinyoung

AU - Kim, Kibeom

AU - Jung-Eun Koh, Katherine

AU - Seo, Jung Eun

AU - Shin, Seock Jae

AU - Choi, Dae Ki

AU - Yoon, Chang Won

AU - Nam, Suk Woo

N1 - Funding Information: This research was supported by the Hydrogen Energy R&D Center, one of the 21st Century Frontier R&D Program, funded by the Ministry of Education, Science and Technology of Korea . Part of this work was also supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP) and by the Ministry of Knowledge Economy (MEST) (the New Renewable Energy Program, NO. 20113030040020 ).

PY - 2013

Y1 - 2013

N2 - Thermally-induced dehydrogenation from a mixture of ammonia borane (AB) and a chemical promoter, tetraethyleneglycol dimethylether (T4EGDE) (AB:T4EGDE = 79:21, wt%) has been demonstrated as an efficient method for hydrogen production at 85-145 °C. We further build on these prior results to create a continuous H2 generator fueled by solid AB beads. The as-developed H2 generator releases ca. 2 equiv of hydrogen autothermally during operation by utilizing excess heat produced from AB dehydrogenation without any external heater. A purifying system equipped with acidic filter materials is further utilized to remove gaseous byproducts other than hydrogen. The H 2 generator shows a rapid H2-release rate up to 3.3 l(H2) min-1 with fast load-following capability. The as-developed H2 generator is ultimately integrated with a commercial 200 We polymer electrolyte membrane fuel cell (PEMFC) to test its capability.

AB - Thermally-induced dehydrogenation from a mixture of ammonia borane (AB) and a chemical promoter, tetraethyleneglycol dimethylether (T4EGDE) (AB:T4EGDE = 79:21, wt%) has been demonstrated as an efficient method for hydrogen production at 85-145 °C. We further build on these prior results to create a continuous H2 generator fueled by solid AB beads. The as-developed H2 generator releases ca. 2 equiv of hydrogen autothermally during operation by utilizing excess heat produced from AB dehydrogenation without any external heater. A purifying system equipped with acidic filter materials is further utilized to remove gaseous byproducts other than hydrogen. The H 2 generator shows a rapid H2-release rate up to 3.3 l(H2) min-1 with fast load-following capability. The as-developed H2 generator is ultimately integrated with a commercial 200 We polymer electrolyte membrane fuel cell (PEMFC) to test its capability.

KW - Ammonia borane

KW - Continuous hydrogen generation

KW - Polymer electrolyte membrane fuel cell

KW - Solvent-mediated thermolysis

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DO - 10.1016/j.jpowsour.2012.11.045

M3 - Article

AN - SCOPUS:84872065414

VL - 229

SP - 170

EP - 178

JO - Journal of Power Sources

JF - Journal of Power Sources

SN - 0378-7753

ER -

Development of a continuous hydrogen generator fueled by ammonia borane for portable fuel cell applications

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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