Development of Au/CeCO2 catalysts for preferential oxidation of CO in PEMFC

Whan Soo Shin, Chang Ryul Jung, Jonghee Han, SukWoo Nam, Tae Hoon Lim, Seong Ahn Hong, Ho In Lee

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The preferential oxidation (PROX) of CO in an H2-rich stream was investigated over Au/MOx (M = Ti, Al, Fe, Ce) catalysts. It was found that 2.5 wt% Au/CeO2 showed the best activity for the reaction. Ceria itself had catalytic activity for the reaction and the activity increased with its decreasing crystallite size. In addition, the effect of Au particle size was investigated by means of XRD, TEM, TPR, and FT-IR spectroscopy of chemisorbed CO. This analysis showed that the number of active sites increased with decreasing Au particle size. This effect caused changes in the intensity of the FT-IR spectra of the adsorbed CO and in the reduction temperature of the catalysts.

Original languageEnglish
Pages (from-to)302-308
Number of pages7
JournalJournal of Industrial and Engineering Chemistry
Volume10
Issue number2
Publication statusPublished - 2004 Dec 1
Externally publishedYes

Fingerprint

Proton exchange membrane fuel cells (PEMFC)
Carbon Monoxide
Particle size
Oxidation
Catalysts
Cerium compounds
Crystallite size
Infrared spectroscopy
Catalyst activity
Transmission electron microscopy
Temperature

Keywords

  • Au particle size
  • CeO crystallite size
  • CO adsorption
  • PEMFC
  • PROX

ASJC Scopus subject areas

  • Chemical Engineering(all)

Cite this

Shin, W. S., Jung, C. R., Han, J., Nam, S., Lim, T. H., Hong, S. A., & Lee, H. I. (2004). Development of Au/CeCO2 catalysts for preferential oxidation of CO in PEMFC. Journal of Industrial and Engineering Chemistry, 10(2), 302-308.

Development of Au/CeCO2 catalysts for preferential oxidation of CO in PEMFC. / Shin, Whan Soo; Jung, Chang Ryul; Han, Jonghee; Nam, SukWoo; Lim, Tae Hoon; Hong, Seong Ahn; Lee, Ho In.

In: Journal of Industrial and Engineering Chemistry, Vol. 10, No. 2, 01.12.2004, p. 302-308.

Research output: Contribution to journalArticle

Shin, WS, Jung, CR, Han, J, Nam, S, Lim, TH, Hong, SA & Lee, HI 2004, 'Development of Au/CeCO2 catalysts for preferential oxidation of CO in PEMFC', Journal of Industrial and Engineering Chemistry, vol. 10, no. 2, pp. 302-308.
Shin, Whan Soo ; Jung, Chang Ryul ; Han, Jonghee ; Nam, SukWoo ; Lim, Tae Hoon ; Hong, Seong Ahn ; Lee, Ho In. / Development of Au/CeCO2 catalysts for preferential oxidation of CO in PEMFC. In: Journal of Industrial and Engineering Chemistry. 2004 ; Vol. 10, No. 2. pp. 302-308.
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