Direct experimental evidence for a metastable state of D2F, an analogue of D3O

Asit B. Raksit, Seung Joon Jeon, Richard F. Porter

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

The D2F radical has been studied by a combination of neutralized ion beam and charge stripping techniques. Neutrals formed by D2F+/Na charge exchange are observed in metastable and dissociative states. The lifetime of metastable D2F is greater than 0.4 μs. Metastability is not observed for HDF or H2F. The dissociative state of D2F releases about 1.9 eV of kinetic energy in its fragmentation products (DF + D). The vertical electron affinity of H2F+ is calculated to be 6.6 ± 0.2 eV. The possibility of observing an emission continuum from electronically excited H2F formed by H2F+/K charge exchange is suggested. Similarities in the mass spectra of D2F and the isoelectronic D3O radical are indicated.

Original languageEnglish
Pages (from-to)2298-2300
Number of pages3
JournalThe Journal of Physical Chemistry®
Volume90
Issue number11
DOIs
Publication statusPublished - 1986
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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