TY - JOUR
T1 - Discriminative detection of indoor volatile organic compounds using a sensor array based on pure and Fe-doped In2O3 nanofibers
AU - Lee, Chul Soon
AU - Li, Hua Yao
AU - Kim, Bo Young
AU - Jo, Young Moo
AU - Byun, Hyung Gi
AU - Hwang, In Sung
AU - Abdel-Hady, Faissal
AU - Wazzan, Abdulaziz A.
AU - Lee, Jong Heun
N1 - Funding Information:
This work was supported by a grant from the National Research Foundation of Korea (NRF) , which was funded by the Korean government (Ministry of Education, Science, and Technology (MEST) , Grant No. 2016R1A2A1A05005331 ).
Publisher Copyright:
© 2019 Elsevier B.V.
PY - 2019/4/15
Y1 - 2019/4/15
N2 - Representative indoor volatile organic compounds (VOCs) such as benzene, xylene, toluene, formaldehyde, and ethanol need to be detected in a highly sensitive and discriminative manner because of their different impact on human health. In this study, pure and 0.05, 0.1, 0.3, and 0.5 at% Fe-doped In2O3 nanofibers were prepared by electrospinning and their gas sensing characteristics toward the aforementioned VOCs were investigated. The doping of In2O3 nanofiber sensor with 0.05 and 0.1 at% Fe shifted the temperature to show the maximum responses to benzene, xylene, and toluene, and reduced responses to ethanol and formaldehyde, thus demonstrating changed gas selectivity. The gas sensing characteristics of 0.5 at% Fe-doped In2O3 nanofiber sensor were substantially different from those of the other sensors. Significantly different gas sensing patterns of pure and Fe-doped In2O3 sensors could be used to discriminate between the five different VOCs at 375 °C and to distinguish between the aromatic and non-aromatic gases at all sensing temperatures. The mechanism underlying the Fe-induced change in gas sensing characteristics has been discussed in relation to the variation of catalytic activity, morphology, oxygen adsorption, and charge carrier concentration.
AB - Representative indoor volatile organic compounds (VOCs) such as benzene, xylene, toluene, formaldehyde, and ethanol need to be detected in a highly sensitive and discriminative manner because of their different impact on human health. In this study, pure and 0.05, 0.1, 0.3, and 0.5 at% Fe-doped In2O3 nanofibers were prepared by electrospinning and their gas sensing characteristics toward the aforementioned VOCs were investigated. The doping of In2O3 nanofiber sensor with 0.05 and 0.1 at% Fe shifted the temperature to show the maximum responses to benzene, xylene, and toluene, and reduced responses to ethanol and formaldehyde, thus demonstrating changed gas selectivity. The gas sensing characteristics of 0.5 at% Fe-doped In2O3 nanofiber sensor were substantially different from those of the other sensors. Significantly different gas sensing patterns of pure and Fe-doped In2O3 sensors could be used to discriminate between the five different VOCs at 375 °C and to distinguish between the aromatic and non-aromatic gases at all sensing temperatures. The mechanism underlying the Fe-induced change in gas sensing characteristics has been discussed in relation to the variation of catalytic activity, morphology, oxygen adsorption, and charge carrier concentration.
KW - Gas sensor
KW - InO
KW - Indoor air quality
KW - Oxide semiconductor
KW - Volatile organic compound
UR - http://www.scopus.com/inward/record.url?scp=85060088219&partnerID=8YFLogxK
U2 - 10.1016/j.snb.2019.01.044
DO - 10.1016/j.snb.2019.01.044
M3 - Article
AN - SCOPUS:85060088219
SN - 0925-4005
VL - 285
SP - 193
EP - 200
JO - Sensors and Actuators, B: Chemical
JF - Sensors and Actuators, B: Chemical
ER -
