Effect of charge-transporting molecules on electrophosphorescence in a device fabricated using third-generation dendrimer encapsulated tris[2-benzo[b]thiophen-2-ylpyridyl]iridium complex

Kyung Moon Jung, Tae Wan Lee, Kyung Hwan Kim, Min Ju Cho, Jung Il Jin, Dong Hoon Choi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

We have synthesized a new deep-red light-emitting phosphorescent third-generation dendrimer with hole-transporting carbazole dendrons. The new dendrimer is highly efficient when used as a solution-processable emitting material and when used in an electrophosphorescent light-emitting diode system. We selected 4,4′-bis(9-carbazolyl)-1,1′-biphenyl (CBP) and 2-(1,1′-biphenyl-4-yl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD) as guest molecules in order to manipulate the carrier transport and carrier confinement in the emissive layer. We fabricated a dendrimer light-emitting diode (DLED) whose configuration is represented as 1TO/PEDOT:PSS (40 nm)/dendrimer containing guest molecules (55 nm)/BCP (2,9-dimethyl-4,7- diphenylphen-anthroline) (10nm)/Alq3 (40nm)/LiF (1 nm)/Al (100nm) and investigated the device performance. The luminance of the multilayered devices fabricated using the PBD-containing dendrimer was 381 cd/m2 at 52.42 mA/cm2 (20 V) for the dendrimer bearing PBD, which was slightly better than that of a device fabricated using dendrimer alone. copyright

Original languageEnglish
Pages (from-to)314-315
Number of pages2
JournalChemistry Letters
Volume38
Issue number4
DOIs
Publication statusPublished - 2009 Jul 20

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Dendrimers
Iridium
Molecules
Light emitting diodes
Bearings (structural)
Carrier transport
Luminance

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Effect of charge-transporting molecules on electrophosphorescence in a device fabricated using third-generation dendrimer encapsulated tris[2-benzo[b]thiophen-2-ylpyridyl]iridium complex. / Jung, Kyung Moon; Lee, Tae Wan; Kim, Kyung Hwan; Cho, Min Ju; Jin, Jung Il; Choi, Dong Hoon.

In: Chemistry Letters, Vol. 38, No. 4, 20.07.2009, p. 314-315.

Research output: Contribution to journalArticle

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