Effect of controlled Mn doping on transition of oxygen vacancies in Bi2Ti2O7 thin films: An electrochemical study

Leeseung Kang, Hye Lan An, Tae Hyung Kim, Duk Hee Lee, Kyung Soo Park, Basudev Swain, Chan Gi Lee, Sahn Nahm

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Crystalline pyrochlore Bi2Ti2O7 (B2T2) thin films were well formed at 300C under 740mTorr of oxygen partial pressure using pulsed laser deposition. In order to improve the electrical properties of the dielectric B2T2 films, Mn ions were doped into the films and their influence was investigated. Improvement in electrical behavior, especially leakage current density were revealed via impedance spectroscopy and electrochemical studies. Mn doping at an appropriate level improved the electrical properties of the films by affording extrinsic oxygen vacancies that reduced the number of intrinsic oxygen vacancies acting as electron trap sites at the interface between the Pt electrode and the B2T2 film. Schottky emission was posited as the leakage current mechanism in the 10 mol% Mn doped B2T2 (Mn:B2T2) films. The barrier height between the Pt electrode and the Mn:B2T2 film was approximately 1.46eV, but decreased to 0.51eV for the non-doped film due to large numbers of intrinsic oxygen vacancies.

Original languageEnglish
JournalApplied Surface Science
DOIs
Publication statusAccepted/In press - 2016 Aug 21

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Keywords

  • BiTiO
  • Leakage current mechanism
  • Metal-insulator-metal capacitor
  • Pyrochlore

ASJC Scopus subject areas

  • Surfaces, Coatings and Films

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