Abstract
The effect of inert coating materials such as Nafion on the non-lithiated LiV3O8 cathode of lithium-metal rechargeable batteries was studied. This uniform and thin coating layer was deposited using electrostatic spray deposition to suppress the crack formation caused by volume expansion and prevent the dissolution of vanadium in the electrolyte. The Nafion coated LiV3O8 electrode exhibited a higher discharge capacity and better capacity retention after 200 cycles (150.86 mAh g−1 and 62.9%, respectively) than the bare LiV3O8 electrode (113.31 mAh g−1 and 46.8%, respectively). The Nafion coated LiV3O8 electrode was characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, and inductively coupled plasma mass spectrometry. Its electrochemical performance was analyzed using a battery testing system and impedance spectroscopy. Our findings show that the inert coating layer on the LiV3O8 cathode plays an important role in improving its electrochemical performance.
| Original language | English |
|---|---|
| Pages (from-to) | 66-73 |
| Number of pages | 8 |
| Journal | Solid State Ionics |
| Volume | 331 |
| DOIs | |
| Publication status | Published - 2019 Mar 1 |
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Keywords
- Electrostatic spray deposition
- Lithium metal battery
- Lithium trivanadate
- Nafion
- Non-lithiated cathode
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Effect of electrostatic spray deposited nafion coating on non-lithiated LiV3O8 cathode in lithium-metal rechargeable batteries. / Bae, Ki Yoon; Kim, Min woo; Kim, Byung Hyuk; Cho, Sung Ho; Yoon, Suk Goo; Yoon, Wooyoung.
In: Solid State Ionics, Vol. 331, 01.03.2019, p. 66-73.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effect of electrostatic spray deposited nafion coating on non-lithiated LiV3O8 cathode in lithium-metal rechargeable batteries
AU - Bae, Ki Yoon
AU - Kim, Min woo
AU - Kim, Byung Hyuk
AU - Cho, Sung Ho
AU - Yoon, Suk Goo
AU - Yoon, Wooyoung
PY - 2019/3/1
Y1 - 2019/3/1
N2 - The effect of inert coating materials such as Nafion on the non-lithiated LiV3O8 cathode of lithium-metal rechargeable batteries was studied. This uniform and thin coating layer was deposited using electrostatic spray deposition to suppress the crack formation caused by volume expansion and prevent the dissolution of vanadium in the electrolyte. The Nafion coated LiV3O8 electrode exhibited a higher discharge capacity and better capacity retention after 200 cycles (150.86 mAh g−1 and 62.9%, respectively) than the bare LiV3O8 electrode (113.31 mAh g−1 and 46.8%, respectively). The Nafion coated LiV3O8 electrode was characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, and inductively coupled plasma mass spectrometry. Its electrochemical performance was analyzed using a battery testing system and impedance spectroscopy. Our findings show that the inert coating layer on the LiV3O8 cathode plays an important role in improving its electrochemical performance.
AB - The effect of inert coating materials such as Nafion on the non-lithiated LiV3O8 cathode of lithium-metal rechargeable batteries was studied. This uniform and thin coating layer was deposited using electrostatic spray deposition to suppress the crack formation caused by volume expansion and prevent the dissolution of vanadium in the electrolyte. The Nafion coated LiV3O8 electrode exhibited a higher discharge capacity and better capacity retention after 200 cycles (150.86 mAh g−1 and 62.9%, respectively) than the bare LiV3O8 electrode (113.31 mAh g−1 and 46.8%, respectively). The Nafion coated LiV3O8 electrode was characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, and inductively coupled plasma mass spectrometry. Its electrochemical performance was analyzed using a battery testing system and impedance spectroscopy. Our findings show that the inert coating layer on the LiV3O8 cathode plays an important role in improving its electrochemical performance.
KW - Electrostatic spray deposition
KW - Lithium metal battery
KW - Lithium trivanadate
KW - Nafion
KW - Non-lithiated cathode
UR - http://www.scopus.com/inward/record.url?scp=85059579434&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85059579434&partnerID=8YFLogxK
U2 - 10.1016/j.ssi.2018.12.020
DO - 10.1016/j.ssi.2018.12.020
M3 - Article
VL - 331
SP - 66
EP - 73
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
ER -