Effect of intertube junctions on the thermoelectric power of monodispersed single walled carbon nanotube networks

Mingxing Piao, Min Kyu Joo, Junhong Na, Yun Jeong Kim, Mireille Mouis, Gérard Ghibaudo, Siegmar Roth, Wung Yeon Kim, Ho Kyun Jang, Gary P. Kennedy, Urszula Dettlaff-Weglikowska, Gyu-Tae Kim

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The thermoelectric power (TEP) of single walled carbon nanotube (SWCNT) thin films in pure metallic SWCNT (m-SWCNT) and pure semiconducting SWCNT (s-SWCNT) networks as well as in m- and s-SWCNT mixtures is investigated. The TEP measured on the pure s-SWCNT film (≈88 μV/K) was found to be almost 7 times higher than that of the m-SWCNTs (≈13 μV/K). Moreover, a quasilinear increase of TEP of the mixed SWCNT networks was observed as the fraction of s-SWCNTs is increased. The experimentally determined relationship between TEP and the fraction of s-SWCNTs in the mixture allows fast and simple quantitative analysis of the s:m ratio in any as-prepared heterogeneous SWCNT network. Furthermore, a semiempirical model analyzing the effect of the intertube junctions is proposed and applied to describe the thermoelectric behavior of the prepared SWCNT networks. The results of calculations match well with the experimental data and clearly demonstrate that the measured TEP of thin SWCNT fi lms is principally controlled by the intertube junctions. The fundamental role of junctions in generating thermoelectric power is not limited to only SWCNT networks as discovered here, but also could be applied to systems where nanoparticles/nanotube form percolating paths in thin films and composite materials.

Original languageEnglish
Pages (from-to)26454-26461
Number of pages8
JournalJournal of Physical Chemistry C
Volume118
Issue number46
DOIs
Publication statusPublished - 2014 Jan 1

Fingerprint

Thermoelectric power
Single-walled carbon nanotubes (SWCN)
carbon nanotubes
Semiconducting films
semiconducting films
Thin films
thin films
Nanotubes
quantitative analysis
nanotubes
Nanoparticles
nanoparticles
composite materials
Composite materials
Chemical analysis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Effect of intertube junctions on the thermoelectric power of monodispersed single walled carbon nanotube networks. / Piao, Mingxing; Joo, Min Kyu; Na, Junhong; Kim, Yun Jeong; Mouis, Mireille; Ghibaudo, Gérard; Roth, Siegmar; Kim, Wung Yeon; Jang, Ho Kyun; Kennedy, Gary P.; Dettlaff-Weglikowska, Urszula; Kim, Gyu-Tae.

In: Journal of Physical Chemistry C, Vol. 118, No. 46, 01.01.2014, p. 26454-26461.

Research output: Contribution to journalArticle

Piao, M, Joo, MK, Na, J, Kim, YJ, Mouis, M, Ghibaudo, G, Roth, S, Kim, WY, Jang, HK, Kennedy, GP, Dettlaff-Weglikowska, U & Kim, G-T 2014, 'Effect of intertube junctions on the thermoelectric power of monodispersed single walled carbon nanotube networks', Journal of Physical Chemistry C, vol. 118, no. 46, pp. 26454-26461. https://doi.org/10.1021/jp505682f
Piao, Mingxing ; Joo, Min Kyu ; Na, Junhong ; Kim, Yun Jeong ; Mouis, Mireille ; Ghibaudo, Gérard ; Roth, Siegmar ; Kim, Wung Yeon ; Jang, Ho Kyun ; Kennedy, Gary P. ; Dettlaff-Weglikowska, Urszula ; Kim, Gyu-Tae. / Effect of intertube junctions on the thermoelectric power of monodispersed single walled carbon nanotube networks. In: Journal of Physical Chemistry C. 2014 ; Vol. 118, No. 46. pp. 26454-26461.
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