Effect of molecular orientation on biodegradability of poly(glycolide-co-ε-caprolactone)

Do Kwang Cho, Jun Wuk Park, Soo Hyun Kim, Young Ha Kim, Seung Soon Im

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The effect of orientation in the amorphous and crystalline region on the biodegradability of linear and star-shaped Poly(glycolide-co-ε-caprolactone)(PGCL) was studied in terms of the crystalline orientation, the crystallinity and thermal properties. Microstructual changes during hydrolysis of the drawn linear and star-shaped PGCL films were investigated using the conventional wide-angle X-ray diffraction equipped a fiber specimen attachment. The drawn star-shaped PGCL showed higher degradation rate than the drawn linear shaped and the degradation decreased with increasing draw ratio. During hydrolysis, the crystallinity for all the samples increased but the crystalline orientation decreased. In particular, the decrement of the crystalline orientation for star-shaped PGCL was higher than that of linear PGCL.

Original languageEnglish
Pages (from-to)223-232
Number of pages10
JournalPolymer Degradation and Stability
Volume80
Issue number2
DOIs
Publication statusPublished - 2003 Jan 1
Externally publishedYes

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Keywords

  • Hydrolytic degradation
  • Microstructural changes
  • Orientation
  • Poly(glycolide-co-ε-caprolactone)
  • Wide-angle X-ray diffraction

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

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