Abstract
Direct formic acid fuel cells (DFAFCs) MEAs were fabricated by using Pt black and Pt/C as cathode catalysts, with various amount of Nafion ionomer. The effect of ionomer content on oxygen reduction reaction (ORR) activities was examined by single cell test, and the MEAs were electrochemically characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Especially the ionic resistances of cathode layers were measured by the complex capacitance analysis of experimental impedance data. The influence of charge transfer reaction on Pt and mass transport of proton and oxygen in the catalyst layers (CL) were discussed for the DFAFC MEAs based on Pt black and Pt/C catalysts.
| Original language | English |
|---|---|
| Journal | ACS National Meeting Book of Abstracts |
| Publication status | Published - 2011 Dec 1 |
| Externally published | Yes |
| Event | 242nd ACS National Meeting and Exposition - Denver, CO, United States Duration: 2011 Aug 28 → 2011 Sep 1 |
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ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
Cite this
Effect of Nafion ionomer and catalyst in cathode layers for the direct formic acid fuel cell with complex capacitance analysis on the ionic resistance. / Jang, Jong Hyun; Kim, Sunhyung; Han, Jonghee; Kwon, Yongchai; Kim, Soo Kil; Lee, Kug Seung; Lee, Byungseok; Lim, Tae Hoon.
In: ACS National Meeting Book of Abstracts, 01.12.2011.Research output: Contribution to journal › Conference article
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TY - JOUR
T1 - Effect of Nafion ionomer and catalyst in cathode layers for the direct formic acid fuel cell with complex capacitance analysis on the ionic resistance
AU - Jang, Jong Hyun
AU - Kim, Sunhyung
AU - Han, Jonghee
AU - Kwon, Yongchai
AU - Kim, Soo Kil
AU - Lee, Kug Seung
AU - Lee, Byungseok
AU - Lim, Tae Hoon
PY - 2011/12/1
Y1 - 2011/12/1
N2 - Direct formic acid fuel cells (DFAFCs) MEAs were fabricated by using Pt black and Pt/C as cathode catalysts, with various amount of Nafion ionomer. The effect of ionomer content on oxygen reduction reaction (ORR) activities was examined by single cell test, and the MEAs were electrochemically characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Especially the ionic resistances of cathode layers were measured by the complex capacitance analysis of experimental impedance data. The influence of charge transfer reaction on Pt and mass transport of proton and oxygen in the catalyst layers (CL) were discussed for the DFAFC MEAs based on Pt black and Pt/C catalysts.
AB - Direct formic acid fuel cells (DFAFCs) MEAs were fabricated by using Pt black and Pt/C as cathode catalysts, with various amount of Nafion ionomer. The effect of ionomer content on oxygen reduction reaction (ORR) activities was examined by single cell test, and the MEAs were electrochemically characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Especially the ionic resistances of cathode layers were measured by the complex capacitance analysis of experimental impedance data. The influence of charge transfer reaction on Pt and mass transport of proton and oxygen in the catalyst layers (CL) were discussed for the DFAFC MEAs based on Pt black and Pt/C catalysts.
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UR - http://www.scopus.com/inward/citedby.url?scp=84861041076&partnerID=8YFLogxK
M3 - Conference article
JO - ACS National Meeting Book of Abstracts
JF - ACS National Meeting Book of Abstracts
SN - 0065-7727
ER -