Abstract
Five new crown ether carboxyhc acid resins have been prepared by condensation polymerization of sym-(R)dibenzo-16-crown-5-oxyacetic acids with formaldehyde. Competitive alkali-metal cation sorption by these novel resins, which contain both ion-exchange and crown ether binding sites for metal ions, has been investigated. As the R-group was varied (methyl, ethyl, propyl, butyl, hexyl and decyl) both the alkali-metal cation sorption selectivity and efficiency were affected. The highest efficiency (loading) and Na+ sorption selectivity were obtained when R = methyl, ethyl and propyl. The longer alkyl groups were found to be detrimental to both sorption efficiency and selectivity.
| Original language | English |
|---|---|
| Pages (from-to) | 1453-1457 |
| Number of pages | 5 |
| Journal | Talanta |
| Volume | 38 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 1991 Dec |
| Externally published | Yes |
ASJC Scopus subject areas
- Analytical Chemistry
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Cite this
Hayashinta, T., Goo, M. J., Kim, J. S., & Bartsch, R. A. (1991). Effect of structural variation within sym-(R)dibenzo-16-crown-5-oxyacetic acid resins upon the selectivity and efficiency of alkali-metal cation sorption. Talanta, 38(12), 1453-1457. https://doi.org/10.1016/0039-9140(91)80295-B