Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni1/3Nb2/3)O3-0. 36PbTiO3-0.23PbZrO3 Ceramics

Cheol Woo Ahn; Sahn Nahm; Jungho Ryu; Kenji Uchino; Seok Jin Yoon; Soon Jong Jung; Jae Sung Song

doi:10.1143/JJAP.43.205

Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni_1/3Nb_2/3)O₃-0. 36PbTiO₃-0.23PbZrO₃ Ceramics

Cheol Woo Ahn, Sahn Nahm, Jungho Ryu, Kenji Uchino, Seok Jin Yoon, Soon Jong Jung, Jae Sung Song

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

ZnO-added 0.41PNN-0.36PT-0.23PZ ceramics cannot be sintered below 950°C. However, when CuO is added, the liquid phase forms and specimens can be sintered even at 850°C. The dielectric constant (ε₃ ^T/ε₀), piezoelectric constant (d₃₃) and electromechanical coupling factor (k_p) increase with the addition of CuO and this is due to the enhancement of the density of the specimens. When CuO is added to 0.41PNN-0.36PT-0.23PZ ceramics, improvements of density, ε₃^T/ε₀, d₃₃ and k _p are also observed. However, the d₃₃ and k_p values of the CuO-added 0.41PNN-0.36PT-0.23PZ ceramics are less than those of the CuO- and ZnO-added specimens. Therefore, ZnO is effective in improving the piezoelectric properties of 0.41PNN-0.36PT-0.23PZ ceramics. Good dielectric and piezoelectric properties of d₃₃=575(pC/N), k_p=0.55 and ε₃^T/ε₀= 3900 are obtained for 0.41PNN-0.36PT-0.23PZ+3.0mol% ZnO with 1 mol% CuO sintered at 900°C for 2 h.

Original language	English
Pages (from-to)	205-210
Number of pages	6
Journal	Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume	43
Issue number	1
DOIs	https://doi.org/10.1143/JJAP.43.205
Publication status	Published - 2004 Jan

Keywords

0.41Pb(NiNb)O-0.36PbTiO -0.23PbZrO ceramics
CuO
Low-temperature sintering
Piezoelectric properties
ZnO

ASJC Scopus subject areas

Engineering(all)
Physics and Astronomy(all)

Access to Document

10.1143/JJAP.43.205

Cite this

Ahn, C. W., Nahm, S., Ryu, J., Uchino, K., Yoon, S. J., Jung, S. J., & Song, J. S. (2004). Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni_1/3Nb_2/3)O₃-0. 36PbTiO₃-0.23PbZrO₃ Ceramics. Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 43(1), 205-210. https://doi.org/10.1143/JJAP.43.205

Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni_1/3Nb_2/3)O₃-0. 36PbTiO₃-0.23PbZrO₃ Ceramics. / Ahn, Cheol Woo; Nahm, Sahn; Ryu, Jungho; Uchino, Kenji; Yoon, Seok Jin; Jung, Soon Jong; Song, Jae Sung.

In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 43, No. 1, 01.2004, p. 205-210.

Research output: Contribution to journal › Article › peer-review

Ahn, CW, Nahm, S, Ryu, J, Uchino, K, Yoon, SJ, Jung, SJ & Song, JS 2004, 'Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni_1/3Nb_2/3)O₃-0. 36PbTiO₃-0.23PbZrO₃ Ceramics', Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, vol. 43, no. 1, pp. 205-210. https://doi.org/10.1143/JJAP.43.205

Ahn, Cheol Woo ; Nahm, Sahn ; Ryu, Jungho ; Uchino, Kenji ; Yoon, Seok Jin ; Jung, Soon Jong ; Song, Jae Sung. / Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni_1/3Nb_2/3)O₃-0. 36PbTiO₃-0.23PbZrO₃ Ceramics. In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers. 2004 ; Vol. 43, No. 1. pp. 205-210.

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abstract = "ZnO-added 0.41PNN-0.36PT-0.23PZ ceramics cannot be sintered below 950°C. However, when CuO is added, the liquid phase forms and specimens can be sintered even at 850°C. The dielectric constant (ε3 T/ε0), piezoelectric constant (d33) and electromechanical coupling factor (kp) increase with the addition of CuO and this is due to the enhancement of the density of the specimens. When CuO is added to 0.41PNN-0.36PT-0.23PZ ceramics, improvements of density, ε3T/ε0, d33 and k p are also observed. However, the d33 and kp values of the CuO-added 0.41PNN-0.36PT-0.23PZ ceramics are less than those of the CuO- and ZnO-added specimens. Therefore, ZnO is effective in improving the piezoelectric properties of 0.41PNN-0.36PT-0.23PZ ceramics. Good dielectric and piezoelectric properties of d33=575(pC/N), kp=0.55 and ε3T/ε0= 3900 are obtained for 0.41PNN-0.36PT-0.23PZ+3.0mol% ZnO with 1 mol% CuO sintered at 900°C for 2 h.",

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AU - Ahn, Cheol Woo

AU - Nahm, Sahn

AU - Ryu, Jungho

AU - Uchino, Kenji

AU - Yoon, Seok Jin

AU - Jung, Soon Jong

AU - Song, Jae Sung

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AB - ZnO-added 0.41PNN-0.36PT-0.23PZ ceramics cannot be sintered below 950°C. However, when CuO is added, the liquid phase forms and specimens can be sintered even at 850°C. The dielectric constant (ε3 T/ε0), piezoelectric constant (d33) and electromechanical coupling factor (kp) increase with the addition of CuO and this is due to the enhancement of the density of the specimens. When CuO is added to 0.41PNN-0.36PT-0.23PZ ceramics, improvements of density, ε3T/ε0, d33 and k p are also observed. However, the d33 and kp values of the CuO-added 0.41PNN-0.36PT-0.23PZ ceramics are less than those of the CuO- and ZnO-added specimens. Therefore, ZnO is effective in improving the piezoelectric properties of 0.41PNN-0.36PT-0.23PZ ceramics. Good dielectric and piezoelectric properties of d33=575(pC/N), kp=0.55 and ε3T/ε0= 3900 are obtained for 0.41PNN-0.36PT-0.23PZ+3.0mol% ZnO with 1 mol% CuO sintered at 900°C for 2 h.

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