Effects of nanocrystalline structure and passivation on the photoluminescent properties of porous silicon carbide

Jonathan E. Spanier, G. S. Cargill, Irving P. Herman, Sangsig Kim, David R. Goldstein, Anthony D. Kurtz, Ben Z. Weiss

Research output: Chapter in Book/Report/Conference proceedingConference contribution

6 Citations (Scopus)


We present the results of an investigation of the dependence of the photoluminescence (PL) spectra on preparation conditions, the resulting microstructure, and post-anodization treatment of porous silicon carbide films which were formed from both p and n-type 6H-SiC substrates. Porous samples were prepared by anodic dissolution under different galvanostatic conditions, resulting in different porosities and crystallite sizes. Selected-area electron diffraction patterns taken on similarly prepared porous silicon carbide (PSC) samples confirmed that the films were monocrystalline. Transmission electron microscopy of as-anodized films revealed an isotropic porous network; a dependence of porosity and nanocrystallite size on porous layer formation current density was established. Some PSC samples were passivated using a short, thermal oxidation treatment. The effects of porosity and crystallite size, and of oxide passivation in these PSC films, on PL spectra and intensity were studied using a 365 nm Kr-ion laser as excitation. Under certain conditions, the spectrally integrated PL intensity of a passivated film is more than 450x that for the original bulk SiC substrate. PL spectra are presented, and possible mechanisms are discussed.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsR.W. Collins, P.M. Fauchet, I. Shimizu, J.C. Vial, T. Shimada, A.P. Alivisatos
PublisherMaterials Research Society
Number of pages6
Publication statusPublished - 1997
Externally publishedYes
EventProceedings of the 1996 MRS Fall Meeting - Boston, MA, USA
Duration: 1996 Dec 21996 Dec 6


OtherProceedings of the 1996 MRS Fall Meeting
CityBoston, MA, USA


ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Spanier, J. E., Cargill, G. S., Herman, I. P., Kim, S., Goldstein, D. R., Kurtz, A. D., & Weiss, B. Z. (1997). Effects of nanocrystalline structure and passivation on the photoluminescent properties of porous silicon carbide. In R. W. Collins, P. M. Fauchet, I. Shimizu, J. C. Vial, T. Shimada, & A. P. Alivisatos (Eds.), Materials Research Society Symposium - Proceedings (Vol. 452, pp. 491-496). Materials Research Society.