Effects of pore structure and PEI impregnation on carbon dioxide adsorption by ZSM-5 zeolites

Chang Hun Lee; Dong Hun Hyeon; Hyunchul Jung; Wonkeun Chung; Dong Hyun Jo; Dong Kun Shin; Sung Hyun Kim

doi:10.1016/j.jiec.2014.08.025

Effects of pore structure and PEI impregnation on carbon dioxide adsorption by ZSM-5 zeolites

Chang Hun Lee, Dong Hun Hyeon, Hyunchul Jung, Wonkeun Chung, Dong Hyun Jo, Dong Kun Shin, Sung Hyun Kim

* Honorary professors

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

The ZSM-5-type zeolites were prepared using three types of structure directing agent to investigate the effect of pore structure and PEI impregnation on the CO₂ adsorption capacity. The CO₂ capacity was primarily affected by the number of the adsorption site and the volume for trapping CO₂. CO₂ was well adsorbed inside the micropore with stronger electric field. The CO₂ capacity increased with increasing amounts of impregnated PEI until PEI loading exceeded the total pore volume, because PEI predominantly occupied the pores of ZSM-5. The ZSM-5 with large surface area and total pore volume was the most favorable for amine-impregnated ZSM-5.

Original language	English
Pages (from-to)	251-256
Number of pages	6
Journal	Journal of Industrial and Engineering Chemistry
Volume	23
DOIs	https://doi.org/10.1016/j.jiec.2014.08.025
Publication status	Published - 2015 Mar 25

Keywords

CO<inf>2</inf> adsorption
Polyethylenimine (PEI)
Structure directing agent (SDA)
ZSM-5 zeolite

ASJC Scopus subject areas

Chemical Engineering(all)

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10.1016/j.jiec.2014.08.025

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title = "Effects of pore structure and PEI impregnation on carbon dioxide adsorption by ZSM-5 zeolites",

abstract = "The ZSM-5-type zeolites were prepared using three types of structure directing agent to investigate the effect of pore structure and PEI impregnation on the CO2 adsorption capacity. The CO2 capacity was primarily affected by the number of the adsorption site and the volume for trapping CO2. CO2 was well adsorbed inside the micropore with stronger electric field. The CO2 capacity increased with increasing amounts of impregnated PEI until PEI loading exceeded the total pore volume, because PEI predominantly occupied the pores of ZSM-5. The ZSM-5 with large surface area and total pore volume was the most favorable for amine-impregnated ZSM-5.",

keywords = "CO<inf>2</inf> adsorption, Polyethylenimine (PEI), Structure directing agent (SDA), ZSM-5 zeolite",

author = "Lee, {Chang Hun} and Hyeon, {Dong Hun} and Hyunchul Jung and Wonkeun Chung and Jo, {Dong Hyun} and Shin, {Dong Kun} and Kim, {Sung Hyun}",

note = "Funding Information: This work was supported by the Korea CCS R&D Center (KCRC) (no. 2014M1A8A1049251 ) grant funded by the Korea government (Ministry of Science, ICT & Future Planning) (no. 2012-0008898 ).",

year = "2015",

month = mar,

day = "25",

doi = "10.1016/j.jiec.2014.08.025",

language = "English",

volume = "23",

pages = "251--256",

journal = "Journal of Industrial and Engineering Chemistry",

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publisher = "Korean Society of Industrial Engineering Chemistry",

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T1 - Effects of pore structure and PEI impregnation on carbon dioxide adsorption by ZSM-5 zeolites

AU - Lee, Chang Hun

AU - Hyeon, Dong Hun

AU - Jung, Hyunchul

AU - Chung, Wonkeun

AU - Jo, Dong Hyun

AU - Shin, Dong Kun

AU - Kim, Sung Hyun

N1 - Funding Information: This work was supported by the Korea CCS R&D Center (KCRC) (no. 2014M1A8A1049251 ) grant funded by the Korea government (Ministry of Science, ICT & Future Planning) (no. 2012-0008898 ).

PY - 2015/3/25

Y1 - 2015/3/25

N2 - The ZSM-5-type zeolites were prepared using three types of structure directing agent to investigate the effect of pore structure and PEI impregnation on the CO2 adsorption capacity. The CO2 capacity was primarily affected by the number of the adsorption site and the volume for trapping CO2. CO2 was well adsorbed inside the micropore with stronger electric field. The CO2 capacity increased with increasing amounts of impregnated PEI until PEI loading exceeded the total pore volume, because PEI predominantly occupied the pores of ZSM-5. The ZSM-5 with large surface area and total pore volume was the most favorable for amine-impregnated ZSM-5.

AB - The ZSM-5-type zeolites were prepared using three types of structure directing agent to investigate the effect of pore structure and PEI impregnation on the CO2 adsorption capacity. The CO2 capacity was primarily affected by the number of the adsorption site and the volume for trapping CO2. CO2 was well adsorbed inside the micropore with stronger electric field. The CO2 capacity increased with increasing amounts of impregnated PEI until PEI loading exceeded the total pore volume, because PEI predominantly occupied the pores of ZSM-5. The ZSM-5 with large surface area and total pore volume was the most favorable for amine-impregnated ZSM-5.

KW - CO<inf>2</inf> adsorption

KW - Polyethylenimine (PEI)

KW - Structure directing agent (SDA)

KW - ZSM-5 zeolite

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U2 - 10.1016/j.jiec.2014.08.025

DO - 10.1016/j.jiec.2014.08.025

M3 - Article

AN - SCOPUS:84928215691

SN - 1226-086X

VL - 23

SP - 251

EP - 256

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

ER -

Effects of pore structure and PEI impregnation on carbon dioxide adsorption by ZSM-5 zeolites

Abstract

Keywords

ASJC Scopus subject areas

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