Effects of water removal on the performance degradation of PEMFCs repetitively brought to <0°C

Eun Ae Cho, Jae Joon Ko, Heung Yong Ha, Seong Ahn Hong, Kwan Young Lee, Tae Won Lim, In Hwan Oh

Research output: Contribution to journalArticlepeer-review

147 Citations (Scopus)

Abstract

For the mobile application, performance of polymer electrolyte membrane fuel cells (PEMFCs) should be maintained with being exposed to subzero temperatures in the winter time. To simulate the situation, a PEMFC was operated at 80°C, stopped, cooled to and kept at -10°C for 1 h, and heated to 80°C for the next operation. With the thermal cycle, cell performance was measured and found to degrade at a degradation rate of 2.3% based on current density at a cell voltage of 0.6 V. The degradation was attributed to freezing of water that was produced during operation and remained in the PEMFC after the operation. To prevent the performance degradation, water was removed from the PEMFC by supplying dry gases or an antifreeze solution to the PEMFC before the cell temperature fell to below 0°C, By using the gas-purging and the solution-purging method designed in this work, the performance degradation rate was successfully reduced to 0.06 and -0.47%, respectively.

Original languageEnglish
Pages (from-to)A661-A665
JournalJournal of the Electrochemical Society
Volume151
Issue number5
DOIs
Publication statusPublished - 2004

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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