Efficiency enhancement of dye-sensitized solar cells by the addition of an oxidizing agent to the TiO2 paste

Kwan Woo Ko, Minoh Lee, S. S. Sekhon, Suresh Kannan Balasingam, Chi Hwan Han, Yongseok Jun

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The addition of various amounts of a strong oxidizing agent (3,5-dinitrosalicyclic acid, DNSA) to TiO2 paste enhances the solar-to-electrical-energy conversion efficiency of the corresponding dye-sensitized solar cells (DSSCs). Maximum performance was obtained from a device that was fabricated by using a TiO2 paste with 2wt % DNSA, which showed a short-circuit current density of 17.88mA cm-2, an open-circuit voltage of 0.78V, and an overall conversion efficiency of 9.62 %, which was an improvement in comparison to reference cells without DNSA. This improvement was rationalized in terms of the amount of residual carbon (formed due to the oxidation of binders) remaining on the TiO2 surface. Addition of a larger amount of oxidizing agent led to a smaller amount of residual carbon on the TiO2 surface. This smaller amount of residual carbon enhanced the adsorption of a larger number of dye molecules on the TiO2 surface. The addition of an oxidizing agent facilitated the removal of more residual organic species during the high-temperature calcination process while causing no change in the surface morphology and microstructure of the TiO2 film. Cut and paste Addition of a strong oxidizing agent (3,5-dinitrosalicylic acid) to the TiO2 paste facilitates the exothermic burning of organic binders during the high temperature calcination process, resulting in smaller amounts of residual carbon. This reduced carbon content facilitates the adsorption of more dye molecules on the TiO2 surface and results in a higher efficiency of the cell.

Original languageEnglish
Pages (from-to)2117-2123
Number of pages7
JournalChemSusChem
Volume6
Issue number11
DOIs
Publication statusPublished - 2013 Nov 1
Externally publishedYes

Fingerprint

Ointments
Oxidants
dye
Carbon
carbon
Acids
acid
Calcination
Conversion efficiency
Binders
Coloring Agents
Dyes
adsorption
Adsorption
Adhesive pastes
Molecules
Open circuit voltage
density current
Energy conversion
Short circuit currents

Keywords

  • dyes/pigments
  • oxidation
  • solar cells
  • surface chemistry
  • titanium oxide

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

Cite this

Efficiency enhancement of dye-sensitized solar cells by the addition of an oxidizing agent to the TiO2 paste. / Ko, Kwan Woo; Lee, Minoh; Sekhon, S. S.; Balasingam, Suresh Kannan; Han, Chi Hwan; Jun, Yongseok.

In: ChemSusChem, Vol. 6, No. 11, 01.11.2013, p. 2117-2123.

Research output: Contribution to journalArticle

Ko, Kwan Woo ; Lee, Minoh ; Sekhon, S. S. ; Balasingam, Suresh Kannan ; Han, Chi Hwan ; Jun, Yongseok. / Efficiency enhancement of dye-sensitized solar cells by the addition of an oxidizing agent to the TiO2 paste. In: ChemSusChem. 2013 ; Vol. 6, No. 11. pp. 2117-2123.
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