Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units

Taek Seung Lee; Jaehwan Lee; Dong Hoon Choi; Soo Young Park; Nakjoong Kim

doi:10.1016/S0014-3057(98)00238-9

Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units

Taek Seung Lee, Jaehwan Lee, Dong Hoon Choi, Soo Young Park, Nakjoong Kim

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.

Original language	English
Pages (from-to)	1197-1201
Number of pages	5
Journal	European Polymer Journal
Volume	35
Issue number	7
DOIs	https://doi.org/10.1016/S0014-3057(98)00238-9
Publication status	Published - 1999
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/S0014-3057(98)00238-9

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title = "Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units",

abstract = "We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.",

author = "Lee, {Taek Seung} and Jaehwan Lee and Choi, {Dong Hoon} and Park, {Soo Young} and Nakjoong Kim",

note = "Funding Information: We are grateful to Dr Taehyoung Zyung at Electronics and Telecommunications Research Institute and Dr Jang Joo Kim at Kwangju Advanced Institute of Science and Technology for refractive index measurements. Financial supports from the KIST 2000 program of Korea Institute of Science and Technology are gratefully acknowledged. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

year = "1999",

doi = "10.1016/S0014-3057(98)00238-9",

language = "English",

volume = "35",

pages = "1197--1201",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Limited",

number = "7",

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T1 - Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units

AU - Lee, Taek Seung

AU - Lee, Jaehwan

AU - Choi, Dong Hoon

AU - Park, Soo Young

AU - Kim, Nakjoong

N1 - Funding Information: We are grateful to Dr Taehyoung Zyung at Electronics and Telecommunications Research Institute and Dr Jang Joo Kim at Kwangju Advanced Institute of Science and Technology for refractive index measurements. Financial supports from the KIST 2000 program of Korea Institute of Science and Technology are gratefully acknowledged. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 1999

Y1 - 1999

N2 - We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.

AB - We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.

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DO - 10.1016/S0014-3057(98)00238-9

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VL - 35

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EP - 1201

JO - European Polymer Journal

JF - European Polymer Journal

IS - 7

ER -

Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units

Abstract

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