Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units

Taek Seung Lee, Jaehwan Lee, Dong Hoon Choi, Soo Young Park, Nakjoong Kim

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.

Original languageEnglish
Pages (from-to)1197-1201
Number of pages5
JournalEuropean Polymer Journal
Volume35
Issue number7
Publication statusPublished - 1999 Dec 1
Externally publishedYes

Fingerprint

crosslinking
Crosslinking
copolymers
Copolymers
Optical properties
Chromophores
optical properties
chromophores
polymers
Electrooptical effects
Polymer matrix
electro-optics
Polymers
harmonics
coefficients
matrices
glycidyl methacrylate

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

Cite this

Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units. / Lee, Taek Seung; Lee, Jaehwan; Choi, Dong Hoon; Park, Soo Young; Kim, Nakjoong.

In: European Polymer Journal, Vol. 35, No. 7, 01.12.1999, p. 1197-1201.

Research output: Contribution to journalArticle

Lee, Taek Seung ; Lee, Jaehwan ; Choi, Dong Hoon ; Park, Soo Young ; Kim, Nakjoong. / Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units. In: European Polymer Journal. 1999 ; Vol. 35, No. 7. pp. 1197-1201.
@article{31961d1b25384c23890c12ffbab4df8e,
title = "Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units",
abstract = "We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90{\%}.",
author = "Lee, {Taek Seung} and Jaehwan Lee and Choi, {Dong Hoon} and Park, {Soo Young} and Nakjoong Kim",
year = "1999",
month = "12",
day = "1",
language = "English",
volume = "35",
pages = "1197--1201",
journal = "European Polymer Journal",
issn = "0014-3057",
publisher = "Elsevier Limited",
number = "7",

}

TY - JOUR

T1 - Electro-optical properties of thermally stable self-crosslinkable copolymer with glycidyl methacrylate units

AU - Lee, Taek Seung

AU - Lee, Jaehwan

AU - Choi, Dong Hoon

AU - Park, Soo Young

AU - Kim, Nakjoong

PY - 1999/12/1

Y1 - 1999/12/1

N2 - We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.

AB - We have investigated electro-optic properties of nonlinear optical polymer with self-crosslinkable groups in the side chain, which we synthesized previously. The system includes crosslinkable epoxy-functionalized copolymer with Tg around 120°C, second harmonic coefficient as high as 45.5 pm/V at 632 nm, and with good temporal stability of the poling-induced chromophore orientation obtained by self-crosslinking reactions in the polymer matrix during the poling process. Successful strategies for simultaneous poling and self-crosslinking during the poling without addition of crosslinking agents are presented. Significant improvement in the temporal stability of chromophore orientation was accomplished up to 90%.

UR - http://www.scopus.com/inward/record.url?scp=0004498033&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0004498033&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0004498033

VL - 35

SP - 1197

EP - 1201

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

IS - 7

ER -