Electrochemical behavior of a silicon monoxide and Li-powder double layer anode cell

Il Won Seong, Wooyoung Yoon

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

A new technique for synthesizing double layer anodes with silicon monoxide and Li powder has been developed to reduce the initial capacity loss of silicon monoxide anodes. Double layer anode (DLA) cells are fabricated using Li emulsified powders on a Cu foil and silicon monoxide powders on a Cu mesh collector and their electrochemical behaviors are studied. The DLA cells show reduced initial irreversibility and enhanced coulombic efficiency. The coulombic efficiency of the first cycle of the DLA cell is over 100% and its capacity remains as 700 mAh g-1 up to 20 cycles. SEM observation shows that the Li-powder layer in DLA compensated for the initial irreversible loss and vanished after several cycles.

Original languageEnglish
Pages (from-to)6143-6147
Number of pages5
JournalJournal of Power Sources
Volume195
Issue number18
DOIs
Publication statusPublished - 2010 Sep 15

Keywords

  • Double layer anode
  • Initial irreversibility
  • Lithium powder
  • Lithium secondary battery
  • Silicon monoxide

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Energy Engineering and Power Technology
  • Renewable Energy, Sustainability and the Environment
  • Physical and Theoretical Chemistry

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