Electrochemical impedance spectroscopic characterization on nano-sized Ca3Co3FeO9 electrode with enhanced capacity retention

Young Dae Ko, Jin Gu Kang, Jae Gwan Park, Dong-Wan Kim

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A Ca3Co3FeO9 electrode exhibiting enhanced cycle-life performance compared to that of Co3O4 was presented in this study. In order to examine the mechanism of the improved capacity retention in the Ca3Co3FeO9 electrode, the cycling-induced variation of electrode kinetics was observed using electrochemical impedance spectroscopy. The separable electrochemical reactions using the appropriate equivalent circuit and the goodness-of-fit results demonstrated the superior charge-transfer kinetics of Ca3Co 3FeO9, compared to Co3O4, during prolonged cycling. These results clearly demonstrated the benefits of the inactive CaO matrix that is spontaneously formed in Ca3Co 3FeO9 during the first discharge process.

Original languageEnglish
Pages (from-to)109-114
Number of pages6
JournalJournal of Applied Electrochemistry
Volume40
Issue number1
DOIs
Publication statusPublished - 2010 Jan 1
Externally publishedYes

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Electrodes
Kinetics
Electrochemical impedance spectroscopy
Equivalent circuits
Charge transfer
Life cycle

Keywords

  • CaCoFeO
  • Capacity retention
  • Charge-transfer kinetics
  • Electrochemical impedance spectroscopy
  • Li-ion batteries

ASJC Scopus subject areas

  • Electrochemistry
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Electrochemical impedance spectroscopic characterization on nano-sized Ca3Co3FeO9 electrode with enhanced capacity retention. / Ko, Young Dae; Kang, Jin Gu; Park, Jae Gwan; Kim, Dong-Wan.

In: Journal of Applied Electrochemistry, Vol. 40, No. 1, 01.01.2010, p. 109-114.

Research output: Contribution to journalArticle

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