Electrochemical properties of nanosized Li2MNO3·li(NI0.8CO0.15Al0.05)O2 composite cathode powders

Jung Hyun Kim, Yun Chan Kang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Nanometer-sized LiNi0.8Co0.15Al0.05O2 and 0.6Li2MnO3·0.4LiNi0.8Co0.15Al0.05O2 powders are prepared by high-temperature flame spray pyrolysis. The 0.6Li2MnO3·0.4LiNi0.8Co0.15Al0.05O2 composite powders post-treated at 700 and 800°C exhibit mixed-layer crystal structures comprising layered Li2MnO3 and layered LiNi0.8Co0.15Al0.05O2 phases. The mean sizes of the composite powders post-treated at 700 and 800°C are 127 and 180 nm, respectively. The layered-layered composite powders have sizes in the nanometer range with a slightly aggregated structure, whereas the layered LiNi0.8Co0.15Al0.05O2 powders have sizes in micrometer range with a hardly aggregated structure. The discharge capacity of the LiNi0.8Co0.15Al0.05O2 powders decreases from 163 to 95 mAh g-1 after 50 cycles with a capacity retention of 58%. The discharge capacity of the 0.6Li2MnO3·0.4LiNi0.8Co0.15Al0.05O2 composite powders decreases from 235 to 200 mAh g-1 after 50 cycles with a capacity retention of 85%.

Original languageEnglish
Pages (from-to)3664-3675
Number of pages12
JournalInternational Journal of Electrochemical Science
Volume8
Issue number3
Publication statusPublished - 2013 Mar 1
Externally publishedYes

Fingerprint

Electrochemical properties
Powders
Cathodes
Composite materials
Spray pyrolysis
Crystal structure

Keywords

  • Cathode material
  • Composite material
  • Flame spray pyrolysis
  • Lithium-rich material
  • Nanomaterials

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Electrochemical properties of nanosized Li2MNO3·li(NI0.8CO0.15Al0.05)O2 composite cathode powders. / Kim, Jung Hyun; Kang, Yun Chan.

In: International Journal of Electrochemical Science, Vol. 8, No. 3, 01.03.2013, p. 3664-3675.

Research output: Contribution to journalArticle

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AB - Nanometer-sized LiNi0.8Co0.15Al0.05O2 and 0.6Li2MnO3·0.4LiNi0.8Co0.15Al0.05O2 powders are prepared by high-temperature flame spray pyrolysis. The 0.6Li2MnO3·0.4LiNi0.8Co0.15Al0.05O2 composite powders post-treated at 700 and 800°C exhibit mixed-layer crystal structures comprising layered Li2MnO3 and layered LiNi0.8Co0.15Al0.05O2 phases. The mean sizes of the composite powders post-treated at 700 and 800°C are 127 and 180 nm, respectively. The layered-layered composite powders have sizes in the nanometer range with a slightly aggregated structure, whereas the layered LiNi0.8Co0.15Al0.05O2 powders have sizes in micrometer range with a hardly aggregated structure. The discharge capacity of the LiNi0.8Co0.15Al0.05O2 powders decreases from 163 to 95 mAh g-1 after 50 cycles with a capacity retention of 58%. The discharge capacity of the 0.6Li2MnO3·0.4LiNi0.8Co0.15Al0.05O2 composite powders decreases from 235 to 200 mAh g-1 after 50 cycles with a capacity retention of 85%.

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