Electrochemical redox properties of chemically synthesized soluble polypyrrole

Y. Son, J. S. Choi, K. S. Jang, J. S. Suh, E. J. Oh, J. Joo, J. H. Cho

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The soluble polypyrrole(PPy) was synthesized and its electrochemical properties were investigated. The polymer was synthesized by oxidative coupling of monomers in aq. (NH4)2;S2O8/dodecylbenzene sulfonic acid(DBSA) at 0°C. The polymer was soluble in various organic solvents. The absorption spectrum change of the DBSA-PPy solution depends on the solvent used. Free standing films cast from these solutions showed amorphous X-ray diffraction pattern and electrical conductivity of 0.1∼6.0 S/cm at room temperature. Thin PPy films on ITO electrodes showed cyclic voltammograms(CV) which have similar shape to those of the electrochemically prepared one. The electrochemical redox properties of these films may be based on the direct reaction of PPy ↔ PPy2+.

Original languageEnglish
Pages (from-to)175-176
Number of pages2
JournalSynthetic Metals
Volume84
Issue number1-3
DOIs
Publication statusPublished - 1997 Jan

Keywords

  • Cyclic voltammogram
  • Electrochemical redox property
  • Soluble polypyrrole

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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  • Cite this

    Son, Y., Choi, J. S., Jang, K. S., Suh, J. S., Oh, E. J., Joo, J., & Cho, J. H. (1997). Electrochemical redox properties of chemically synthesized soluble polypyrrole. Synthetic Metals, 84(1-3), 175-176. https://doi.org/10.1016/s0379-6779(97)80700-x