Enantioselective syntheses of decursinol angelate and decursin

Jongdoo Lim, Ik Hwan Kim, Hyeon H. Kim, Kyung Seop Ahn, Hogyu Han

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step.

Original languageEnglish
Pages (from-to)4001-4003
Number of pages3
JournalTetrahedron Letters
Volume42
Issue number24
DOIs
Publication statusPublished - 2001 Jun 11

Fingerprint

Stereochemistry
Epoxidation
decursin
resorcinol
Mn-salen

Keywords

  • Catalytic asymmetric epoxidation
  • Decursin
  • Decursinol
  • Decursinol angelate
  • Protein kinase C

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Enantioselective syntheses of decursinol angelate and decursin. / Lim, Jongdoo; Kim, Ik Hwan; Kim, Hyeon H.; Ahn, Kyung Seop; Han, Hogyu.

In: Tetrahedron Letters, Vol. 42, No. 24, 11.06.2001, p. 4001-4003.

Research output: Contribution to journalArticle

Lim, Jongdoo ; Kim, Ik Hwan ; Kim, Hyeon H. ; Ahn, Kyung Seop ; Han, Hogyu. / Enantioselective syntheses of decursinol angelate and decursin. In: Tetrahedron Letters. 2001 ; Vol. 42, No. 24. pp. 4001-4003.
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