Endoergic reactions of hyperthermal C(3P) with methane and acetylene

M. R. Scholefield, Jong-Ho Choi, S. Goyal, H. Reisler

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Endoergic reaction channels of C(3P) with CH4 and C2H2 have been studied by using free laser ablation of graphite for preparation of hyperthermal (>2 eV) C(3P). Energy distributions in the CH products are determined and compared with those obtained in other reactions of C(3P). It is suggested that both reactions proceed via carbene intermediates, but the specific mechanisms of the two reactions are different.

Original languageEnglish
Pages (from-to)487-493
Number of pages7
JournalChemical Physics Letters
Volume288
Issue number2-4
Publication statusPublished - 1998 May 22

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Acetylene
Graphite
Methane
Laser ablation
acetylene
methane
carbenes
laser ablation
energy distribution
graphite
methylidyne
preparation
carbene
products

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Scholefield, M. R., Choi, J-H., Goyal, S., & Reisler, H. (1998). Endoergic reactions of hyperthermal C(3P) with methane and acetylene. Chemical Physics Letters, 288(2-4), 487-493.

Endoergic reactions of hyperthermal C(3P) with methane and acetylene. / Scholefield, M. R.; Choi, Jong-Ho; Goyal, S.; Reisler, H.

In: Chemical Physics Letters, Vol. 288, No. 2-4, 22.05.1998, p. 487-493.

Research output: Contribution to journalArticle

Scholefield, MR, Choi, J-H, Goyal, S & Reisler, H 1998, 'Endoergic reactions of hyperthermal C(3P) with methane and acetylene', Chemical Physics Letters, vol. 288, no. 2-4, pp. 487-493.
Scholefield MR, Choi J-H, Goyal S, Reisler H. Endoergic reactions of hyperthermal C(3P) with methane and acetylene. Chemical Physics Letters. 1998 May 22;288(2-4):487-493.
Scholefield, M. R. ; Choi, Jong-Ho ; Goyal, S. ; Reisler, H. / Endoergic reactions of hyperthermal C(3P) with methane and acetylene. In: Chemical Physics Letters. 1998 ; Vol. 288, No. 2-4. pp. 487-493.
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