Abstract
Endoergic reaction channels of C(3P) with CH4 and C2H2 have been studied by using free laser ablation of graphite for preparation of hyperthermal (>2 eV) C(3P). Energy distributions in the CH products are determined and compared with those obtained in other reactions of C(3P). It is suggested that both reactions proceed via carbene intermediates, but the specific mechanisms of the two reactions are different.
| Original language | English |
|---|---|
| Pages (from-to) | 487-493 |
| Number of pages | 7 |
| Journal | Chemical Physics Letters |
| Volume | 288 |
| Issue number | 2-4 |
| Publication status | Published - 1998 May 22 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
Endoergic reactions of hyperthermal C(3P) with methane and acetylene. / Scholefield, M. R.; Choi, Jong-Ho; Goyal, S.; Reisler, H.
In: Chemical Physics Letters, Vol. 288, No. 2-4, 22.05.1998, p. 487-493.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Endoergic reactions of hyperthermal C(3P) with methane and acetylene
AU - Scholefield, M. R.
AU - Choi, Jong-Ho
AU - Goyal, S.
AU - Reisler, H.
PY - 1998/5/22
Y1 - 1998/5/22
N2 - Endoergic reaction channels of C(3P) with CH4 and C2H2 have been studied by using free laser ablation of graphite for preparation of hyperthermal (>2 eV) C(3P). Energy distributions in the CH products are determined and compared with those obtained in other reactions of C(3P). It is suggested that both reactions proceed via carbene intermediates, but the specific mechanisms of the two reactions are different.
AB - Endoergic reaction channels of C(3P) with CH4 and C2H2 have been studied by using free laser ablation of graphite for preparation of hyperthermal (>2 eV) C(3P). Energy distributions in the CH products are determined and compared with those obtained in other reactions of C(3P). It is suggested that both reactions proceed via carbene intermediates, but the specific mechanisms of the two reactions are different.
UR - http://www.scopus.com/inward/record.url?scp=0032557311&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032557311&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0032557311
VL - 288
SP - 487
EP - 493
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 2-4
ER -