Enhanced Chemical Reactivity of Graphene by Fermi Level Modulation

Myung Jin Park, Hae Hyun Choi, Baekwon Park, Jae Yoon Lee, Chul-Ho Lee, Yong Seok Choi, Youngsoo Kim, Je Min Yoo, Hyukjin Lee, Byung Hee Hong

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Among various approaches to modify the electronic and chemical properties of graphene, functionalization is one of the most facile ways to tailor these properties. The rearranged structure with covalently bonded diazonium molecules exhibits distinct semiconducting property, and the attached diazonium enables subsequent chemical reactions. Notably, the rate of diazonium functionalization depends on the substrate and the presence of strain. Meanwhile, according to the Gerischer-Marcus theory, this reactivity can be further tuned by adjusting the Fermi level. Here, we precisely controlled the Fermi level of graphene by introducing the self-assembled monolayer (SAM) and investigated the degree of chemical reactivity of graphene with respect to the doping types. The n-doped graphene exhibited the highest reactivity not only for diazonium molecules but also for metal ions. The increased reactivity is originated from a remarkable electron donor effect over the entire area. In addition, the n-doped graphene enabled spatially patterned functionalization of diazonium molecules, which was further utilized as a growth template for gold particles that would be advantageous for enhanced electrochemical reactivity.

Original languageEnglish
Pages (from-to)5602-5609
Number of pages8
JournalChemistry of Materials
Volume30
Issue number16
DOIs
Publication statusPublished - 2018 Aug 28

Fingerprint

Chemical reactivity
Graphite
Fermi level
Graphene
Modulation
Molecules
Self assembled monolayers
Gold
Electronic properties
Chemical properties
Metal ions
Chemical reactions
Doping (additives)
Electrons
Substrates

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Park, M. J., Choi, H. H., Park, B., Lee, J. Y., Lee, C-H., Choi, Y. S., ... Hong, B. H. (2018). Enhanced Chemical Reactivity of Graphene by Fermi Level Modulation. Chemistry of Materials, 30(16), 5602-5609. https://doi.org/10.1021/acs.chemmater.8b01614

Enhanced Chemical Reactivity of Graphene by Fermi Level Modulation. / Park, Myung Jin; Choi, Hae Hyun; Park, Baekwon; Lee, Jae Yoon; Lee, Chul-Ho; Choi, Yong Seok; Kim, Youngsoo; Yoo, Je Min; Lee, Hyukjin; Hong, Byung Hee.

In: Chemistry of Materials, Vol. 30, No. 16, 28.08.2018, p. 5602-5609.

Research output: Contribution to journalArticle

Park, MJ, Choi, HH, Park, B, Lee, JY, Lee, C-H, Choi, YS, Kim, Y, Yoo, JM, Lee, H & Hong, BH 2018, 'Enhanced Chemical Reactivity of Graphene by Fermi Level Modulation', Chemistry of Materials, vol. 30, no. 16, pp. 5602-5609. https://doi.org/10.1021/acs.chemmater.8b01614
Park, Myung Jin ; Choi, Hae Hyun ; Park, Baekwon ; Lee, Jae Yoon ; Lee, Chul-Ho ; Choi, Yong Seok ; Kim, Youngsoo ; Yoo, Je Min ; Lee, Hyukjin ; Hong, Byung Hee. / Enhanced Chemical Reactivity of Graphene by Fermi Level Modulation. In: Chemistry of Materials. 2018 ; Vol. 30, No. 16. pp. 5602-5609.
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