Enzymatic coproduction of biodiesel and glycerol carbonate from soybean oil and dimethyl carbonate

Pil Je Seong, Byoung Wook Jeon, Myunggu Lee, Dae Haeng Cho, Duk Ki Kim, Kwang S. Jung, Seung Wook Kim, Sung Ok Han, Yong Hwan Kim, Chulhwan Park

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

The enzymatic coproduction of biodiesel and glycerol carbonate by the transesterification of soybean oil was studied using lipase as catalyst in organic solvent. To produce biodiesel and glycerol carbonate simultaneously, experiments were designed sequentially. Enzyme screening, the molar ratio of dimethyl carbonate (DMC) to soybean oil, reaction temperature and solvent effects were investigated. The results of enzyme screening, at 100. g/L Novozym 435 (immobilized Candida antarctica lipase B), biodiesel and glycerol carbonate showed conversions of 58.7% and 50.7%, respectively. The optimal conditions were 60 °C, 100. g/L Novozym 435, 6.0:1 molar ratio with tert-butanol as solvent: 84.9% biodiesel and 92.0% glycerol carbonate production was achieved.

Original languageEnglish
Pages (from-to)505-509
Number of pages5
JournalEnzyme and Microbial Technology
Volume48
Issue number6-7
DOIs
Publication statusPublished - 2011 May 6

Keywords

  • Biodiesel
  • Coproduction
  • Dimethyl carbonate
  • Glycerol carbonate
  • Tert-Butanol

ASJC Scopus subject areas

  • Biotechnology
  • Bioengineering
  • Biochemistry
  • Applied Microbiology and Biotechnology

Fingerprint Dive into the research topics of 'Enzymatic coproduction of biodiesel and glycerol carbonate from soybean oil and dimethyl carbonate'. Together they form a unique fingerprint.

Cite this