Evaluation of direct formic acid fuel cells with catalyst layers coated by electrospray

Yongchai Kwon, Seungmin Baek, Byungwan Kwon, Jinsoo Kim, Jonghee Han

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

We investigated cell performance and performed phenomenological analyses of direct formic acid fuel cells (DFAFCs) incorporating anode (palladium) and cathode (platinum) catalysts prepared using a new electrospray coating technique. To optimize the design of the DFAFC, we examined the cell performance by the Pd catalyst loading and formic acid feed rate. Of Pd catalyst loaded samples, 3 mg/cm2 sample showed the highest electrical performance with formic acid feed rate of 5 ml/min. This behavior was caused by discrepancies in the mass transfer limitation. When the feed rate was greater than 10 mL/min, however, the 7 mg/cm2 sample provided the highest electrical performance, which was attributed to enhanced electrooxidation reactions. For comparison of the effect of the catalyst coating method on the cell performance of DFAFC, polarization curves of the DFAFC incorporating catalysts prepared using a conventional airspray coating method were also measured. As a result of the comparison, the electrospray coatingused DFAFC showed better cell performance. Based on these results, the cell performance of the DFAFCs was optimized when the catalysts using the electrospray catalyst coating were employed, the amount of Pd loaded on the anode electrode was 3 mg/cm2 (Pd thickness: ~6 μm), and the formic acid feed rate was 10 mL/min.

Original languageEnglish
Pages (from-to)836-842
Number of pages7
JournalKorean Journal of Chemical Engineering
Volume27
Issue number3
DOIs
Publication statusPublished - 2010 Apr 1
Externally publishedYes

Fingerprint

Formic acid fuel cells (FAFC)
formic acid
Catalysts
Formic acid
Coatings
Anodes
Coating techniques
Electrooxidation
Palladium
Platinum
Cathodes
Mass transfer
Polarization
Electrodes

Keywords

  • Direct Formic Acid Fuel Cell
  • Electrooxidation
  • Electrospray
  • Mass Transfer

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Evaluation of direct formic acid fuel cells with catalyst layers coated by electrospray. / Kwon, Yongchai; Baek, Seungmin; Kwon, Byungwan; Kim, Jinsoo; Han, Jonghee.

In: Korean Journal of Chemical Engineering, Vol. 27, No. 3, 01.04.2010, p. 836-842.

Research output: Contribution to journalArticle

Kwon, Yongchai ; Baek, Seungmin ; Kwon, Byungwan ; Kim, Jinsoo ; Han, Jonghee. / Evaluation of direct formic acid fuel cells with catalyst layers coated by electrospray. In: Korean Journal of Chemical Engineering. 2010 ; Vol. 27, No. 3. pp. 836-842.
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