Exploring the dynamics of hydrogen atom release from the radical-radical reaction of O(3P) with C3H5

Sun Kyu Joo; Lee Kyoung Kwon; Hohjai Lee; Jong Ho Choi

doi:10.1063/1.1688319

Exploring the dynamics of hydrogen atom release from the radical-radical reaction of O(³P) with C₃H₅

Sun Kyu Joo, Lee Kyoung Kwon, Hohjai Lee, Jong Ho Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The dynamics of hydrogen atom release from the radical-radical reaction of O(³P) with C₃H₅ was investigated. The vacuum-ultraviolet-laser induced fluorescence (VUV-LIF) spectroscopy in a crossed beam configuration was used for the study. statistical calculations and CBS-QB3 level of ab initio theory were also applied to analyze the reaction dynamics. It was observed that the formation of H(²S)+C ₃H₄O was the major reaction pathway and counterpart product of the probed hydrogen atom was acrolein.

Original language	English
Pages (from-to)	7976-7982
Number of pages	7
Journal	Journal of Chemical Physics
Volume	120
Issue number	17
DOIs	https://doi.org/10.1063/1.1688319
Publication status	Published - 2004 May 1

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1688319

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Exploring the dynamics of hydrogen atom release from the radical-radical reaction of O(³P) with C₃H₅

Abstract

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