Facile performance enhancement of reverse osmosis membranes via solvent activation with benzyl alcohol

Min Gyu Shin, Sang Hee Park, Soon Jin Kwon, Hyo Eun Kwon, Jong Bae Park, Jung-hyun Lee

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

We present a facile method to enhance separation performance of polyamide (PA) reverse osmosis (RO) membranes via solvent activation with a new type of organic solvent, benzyl alcohol (BA). Activation with BA remarkably improved water permeance (up to ∼140% increase) while maintaining high NaCl rejection (∼99.6%) of the pristine RO membrane, thereby overcoming the flux-rejection trade-off limitation. Thus, the water permeance and permselectivity of the BA-activated RO membrane significantly exceeded those of commercial RO membranes. This significant performance enhancement was attributed to the appropriate solvency power of BA (determined based on Hansen solubility parameters), which led to the balanced structural deformation of the PA selective layer; BA activation produced a less dense and highly permeable PA structure by greatly swelling PA, while simultaneously healing loosened sites via structural compaction of the PA network with a sufficiently reduced modulus. Based on the activation results with various organic solvents ranging from mild to strong solvents, we propose a more reliable predictor of the solvent activation effect. Our strategy is a simple, effective and commercially viable method to enhance RO membrane performance. Additionally, our study highlights on the underlying solvent activating mechanism of PA RO membranes.

Original languageEnglish
Pages (from-to)220-229
Number of pages10
JournalJournal of Membrane Science
Volume578
DOIs
Publication statusPublished - 2019 May 15

Fingerprint

Osmosis
reverse osmosis
Benzyl Alcohol
Osmosis membranes
Nylons
Reverse osmosis
Polyamides
alcohols
Alcohols
Chemical activation
activation
membranes
Membranes
augmentation
rejection
Organic solvents
Water
healing
swelling
Solubility

Keywords

  • Benzyl alcohol
  • Interfacial polymerization
  • Polyamide thin film composite membrane
  • Reverse osmosis
  • Solvent activation

ASJC Scopus subject areas

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

Facile performance enhancement of reverse osmosis membranes via solvent activation with benzyl alcohol. / Shin, Min Gyu; Park, Sang Hee; Kwon, Soon Jin; Kwon, Hyo Eun; Park, Jong Bae; Lee, Jung-hyun.

In: Journal of Membrane Science, Vol. 578, 15.05.2019, p. 220-229.

Research output: Contribution to journalArticle

Shin, Min Gyu ; Park, Sang Hee ; Kwon, Soon Jin ; Kwon, Hyo Eun ; Park, Jong Bae ; Lee, Jung-hyun. / Facile performance enhancement of reverse osmosis membranes via solvent activation with benzyl alcohol. In: Journal of Membrane Science. 2019 ; Vol. 578. pp. 220-229.
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