Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned iron(III) cyanide precursor

Il Kim Jae; Sik Yoo Houng; Kwan Kon Eui; Chan Kim Hyoung; Seop Hong Chang

doi:10.1021/ic701361a

Ferrimagnetic Fe^III-Mn^III zigzag chain formed by a new mer-positioned iron(III) cyanide precursor

Il Kim Jae, Sik Yoo Houng, Kwan Kon Eui, Chan Kim Hyoung, Seop Hong Chang

Department of Chemistry

Research output: Contribution to journal › Article

68 Citations (Scopus)

Abstract

A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) ₃]^- (1), and a zigzag chain, [Fe(pzcq)(CN) ₃][Mn(salen)]·4H₂O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

Original language	English
Pages (from-to)	8481-8483
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	21
DOIs	https://doi.org/10.1021/ic701361a
Publication status	Published - 2007 Oct 15

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned iron(III) cyanide precursor",

abstract = "A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) 3]- (1), and a zigzag chain, [Fe(pzcq)(CN) 3][Mn(salen)]·4H2O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.",

author = "Jae, {Il Kim} and Houng, {Sik Yoo} and Eui, {Kwan Kon} and Hyoung, {Chan Kim} and Chang, {Seop Hong}",

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T1 - Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned iron(III) cyanide precursor

AU - Jae, Il Kim

AU - Houng, Sik Yoo

AU - Eui, Kwan Kon

AU - Hyoung, Chan Kim

AU - Chang, Seop Hong

PY - 2007/10/15

Y1 - 2007/10/15

N2 - A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) 3]- (1), and a zigzag chain, [Fe(pzcq)(CN) 3][Mn(salen)]·4H2O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

AB - A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) 3]- (1), and a zigzag chain, [Fe(pzcq)(CN) 3][Mn(salen)]·4H2O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

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