Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned iron(III) cyanide precursor

Il Kim Jae; Sik Yoo Houng; Kwan Kon Eui; Chan Kim Hyoung; Chang Seop Hong

doi:10.1021/ic701361a

Ferrimagnetic Fe^III-Mn^III zigzag chain formed by a new mer-positioned iron(III) cyanide precursor

Il Kim Jae, Sik Yoo Houng, Kwan Kon Eui, Chan Kim Hyoung, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article

67 Citations (Scopus)

Abstract

A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) ₃]^- (1), and a zigzag chain, [Fe(pzcq)(CN) ₃][Mn(salen)]·4H₂O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

Original language	English
Pages (from-to)	8481-8483
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	21
DOIs	https://doi.org/10.1021/ic701361a
Publication status	Published - 2007 Oct 15

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ASJC Scopus subject areas

Inorganic Chemistry

Cite this

Jae, I. K., Houng, S. Y., Eui, K. K., Hyoung, C. K., & Hong, C. S. (2007). Ferrimagnetic Fe^III-Mn^III zigzag chain formed by a new mer-positioned iron(III) cyanide precursor. Inorganic Chemistry, 46(21), 8481-8483. https://doi.org/10.1021/ic701361a

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abstract = "A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) 3]- (1), and a zigzag chain, [Fe(pzcq)(CN) 3][Mn(salen)]·4H2O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.",

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AU - Hyoung, Chan Kim

AU - Hong, Chang Seop

PY - 2007/10/15

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AB - A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN) 3]- (1), and a zigzag chain, [Fe(pzcq)(CN) 3][Mn(salen)]·4H2O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

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10.1021/ic701361a