Ferrocene-appended aryl triazole for electrochemical recognition of phosphate ions

Qian Yong Cao, Tuhin Pradhan, Sungtae Kim, Jong Seung Kim

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C-H•••O) with a tetrahedral anion, which is supported by density functional theory based theoretical calculation and 1H NMR titration results.

Original languageEnglish
Pages (from-to)4386-4389
Number of pages4
JournalOrganic Letters
Volume13
Issue number16
DOIs
Publication statusPublished - 2011 Aug 19

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Triazoles
Anions
phosphates
Phosphates
Ions
anions
ions
Titration
titration
Density functional theory
Nuclear magnetic resonance
X-Rays
density functional theory
X rays
nuclear magnetic resonance
Crystals
ferrocene
crystals
x rays

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

Cite this

Ferrocene-appended aryl triazole for electrochemical recognition of phosphate ions. / Cao, Qian Yong; Pradhan, Tuhin; Kim, Sungtae; Kim, Jong Seung.

In: Organic Letters, Vol. 13, No. 16, 19.08.2011, p. 4386-4389.

Research output: Contribution to journalArticle

Cao, Qian Yong ; Pradhan, Tuhin ; Kim, Sungtae ; Kim, Jong Seung. / Ferrocene-appended aryl triazole for electrochemical recognition of phosphate ions. In: Organic Letters. 2011 ; Vol. 13, No. 16. pp. 4386-4389.
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