Field-induced metamagnetic transition in the FeIII-Mn III bimetallic chain built by a new cyanide-bearing FeIII precursor

Il Kim Jae; Sik Yoo Houng; Kwan Koh Eui; Seop Hong Chang

doi:10.1021/ic702001q

Field-induced metamagnetic transition in the Fe^III-Mn ^III bimetallic chain built by a new cyanide-bearing Fe^III precursor

Il Kim Jae, Sik Yoo Houng, Kwan Koh Eui, Seop Hong Chang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The use of a new precursor, mer-[Fe(mpzcq)(CN)₃]^- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)₃][Mn(salen)(H ₂O)]·H₂O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)₃][Mn(salcy)]· MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.

Original language	English
Pages (from-to)	10461-10463
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	25
DOIs	https://doi.org/10.1021/ic702001q
Publication status	Published - 2007 Dec 10

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Field-induced metamagnetic transition in the FeIII-Mn III bimetallic chain built by a new cyanide-bearing FeIII precursor",

abstract = "The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H 2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]· MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.",

author = "Jae, {Il Kim} and Houng, {Sik Yoo} and Eui, {Kwan Koh} and Chang, {Seop Hong}",

year = "2007",

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doi = "10.1021/ic702001q",

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volume = "46",

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journal = "Inorganic Chemistry",

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T1 - Field-induced metamagnetic transition in the FeIII-Mn III bimetallic chain built by a new cyanide-bearing FeIII precursor

AU - Jae, Il Kim

AU - Houng, Sik Yoo

AU - Eui, Kwan Koh

AU - Chang, Seop Hong

PY - 2007/12/10

Y1 - 2007/12/10

N2 - The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H 2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]· MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.

AB - The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H 2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]· MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.

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U2 - 10.1021/ic702001q

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VL - 46

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EP - 10463

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 25

ER -

Field-induced metamagnetic transition in the Fe^III-Mn ^III bimetallic chain built by a new cyanide-bearing Fe^III precursor

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