Field-induced metamagnetic transition in the FeIII-Mn III bimetallic chain built by a new cyanide-bearing FeIII precursor

Il Kim Jae, Sik Yoo Houng, Kwan Koh Eui, Seop Hong Chang

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H 2O)]·H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)]· MeOH·MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.

Original languageEnglish
Pages (from-to)10461-10463
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number25
DOIs
Publication statusPublished - 2007 Dec 10

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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