Fine-sized LiCoO2 particles prepared by spray pyrolysis from polymeric precursor solution

Do Youp Kim, Seo Hee Ju, Yun Chan Kang

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Fine-sized LiCoO2 particles with high discharge capacities and good cycle properties were prepared by spray pyrolysis from a spray solution with citric acid and ethylene glycol. The precursor particles obtained from the spray solution with citric acid and ethylene glycol transformed into fine-sized LiCoO2 particles with regular morphology after post-treatment at temperatures between 700 and 900 °C. The mean size and aggregation degree of the primary particles were affected by the concentrations of polymeric precursors added into spray solutions. The LiCoO2 particles obtained from the spray solution without polymeric precursors had irregular and aggregated morphology. The discharge capacities of the LiCoO2 particles changed from 132 to 151 mAh/g when the concentrations of the citric acid and ethylene glycol changed from 0 to 1 M. The particles prepared from the spray solution containing 0.3 M each of citric acid and ethylene glycol had the maximum discharge intensity.

Original languageEnglish
Pages (from-to)362-370
Number of pages9
JournalMaterials Research Bulletin
Volume42
Issue number2
DOIs
Publication statusPublished - 2007 Feb 15
Externally publishedYes

Fingerprint

Spray pyrolysis
Ethylene Glycol
pyrolysis
sprayers
Citric acid
Ethylene glycol
Citric Acid
citric acid
glycols
ethylene
Discharge (fluid mechanics)
Agglomeration
cycles
Temperature

Keywords

  • A. Electronic materials
  • B. Chemical synthesis
  • D. Electrochemical properties

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Fine-sized LiCoO2 particles prepared by spray pyrolysis from polymeric precursor solution. / Kim, Do Youp; Ju, Seo Hee; Kang, Yun Chan.

In: Materials Research Bulletin, Vol. 42, No. 2, 15.02.2007, p. 362-370.

Research output: Contribution to journalArticle

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