First hyperpolarizabilities of hexa(ethynyl)benzene derivatives: Effect of conjugation length

Ming Jun Piao, Khalil Chajara, Soo Jung Yoon, Hwan Myung Kim, Seung Joon Jeon, Tae Hyun Kim, Kai Song, Inge Asselberghs, André Persoons, Koen Clays, Bong Rae Cho

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A variety of dipolar and octupolar molecules containing CC bonds as the conjugation bridge have been synthesized and the linear and nonlinear optical properties (β) were studied. The β(0) value of the dipole increases with conjugation length, whereas that of the octupole decreases from 2a to 2b with concomitant decrease in λmax. A further increase in the conjugation length to 3a-c increased β(0) because of the larger oscillator strength. Moreover, 3a with the most distorted structure shows the largest β(0), probably because of the dipolar contribution. On the other hand, βyyyzzz ratios are smaller than unity, probably because βzzz is overestimated by the errors involved in the resonance correction.

Original languageEnglish
Pages (from-to)2273-2281
Number of pages9
JournalJournal of Materials Chemistry
Volume16
Issue number23
DOIs
Publication statusPublished - 2006

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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    Piao, M. J., Chajara, K., Yoon, S. J., Kim, H. M., Jeon, S. J., Kim, T. H., Song, K., Asselberghs, I., Persoons, A., Clays, K., & Cho, B. R. (2006). First hyperpolarizabilities of hexa(ethynyl)benzene derivatives: Effect of conjugation length. Journal of Materials Chemistry, 16(23), 2273-2281. https://doi.org/10.1039/b601982j