Flowable polysilsesquioxanes as robust solvent-free optical hard coatings

Min Hyuk Choi, Jin Young Seo, Jungbin Ahn, Han Young Woo, Sangho Cho, Seung Sang Hwang, Albert S. Lee, Kyung Youl Baek

Research output: Contribution to journalArticlepeer-review

Abstract

Pourable and room temperature flowable ladder-structured polysilsesquioxanes were synthesized and applied as functional optical hard coatings. Organic functional group type (propyl, hexyl, octyl, dodecyl) and their copolymer composition with UV-curable methylacryloxypropyl group were selected as to control both pre-cured viscosity and final mechanical properties independent of molecular weight. Ladder-structured polysilsesquioxanes with longer alkyl side chains exhibited higher fluidity and flexibility while maintaining its optical property and mechanical strength. The solvent-free processability of our synthesized materials along with their superior optical and mechanical properties over commercial solvent-based hard coatings suggest the high value of our hybrid materials for the coatings industry.

Original languageEnglish
Article number105030
JournalReactive and Functional Polymers
Volume167
DOIs
Publication statusPublished - 2021 Oct

Keywords

  • Hard coating
  • Ladder-like poly(silsesquioxane)
  • Solvent-free processing

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Biochemistry
  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

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