Fluorescent ratiometry of tetrahomodioxacalix[4]arene pyrenylamides upon cation complexation

Jung Kyu Choi, Areum Lee, Seyoung Kim, Sihyun Ham, Kwanghyun No, Jong Seung Kim

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

C-1,2-alternate tetrahomodioxacalix[4]arene pyreneamides were synthesized. Pb2+ coordination gave a quenched monomer and excimer fluorescence emission, while upon Ca2+ ion binding, the receptor provides an enhanced excimer and declined monomer emission with ratiometric response. The excimer emission spectra changes are rationalized by frontier molecular orbitals that the effective Py-Py* interaction induces emission intensity increases upon Ca2+ ion complexation, whereas there is no such interaction observed upon Pb2+ binding.

Original languageEnglish
Pages (from-to)1601-1604
Number of pages4
JournalOrganic Letters
Volume8
Issue number8
DOIs
Publication statusPublished - 2006 Apr 13
Externally publishedYes

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excimers
Complexation
Cations
Monomers
Ions
cations
Molecular orbitals
monomers
Fluorescence
molecular orbitals
ions
emission spectra
interactions
fluorescence

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Fluorescent ratiometry of tetrahomodioxacalix[4]arene pyrenylamides upon cation complexation. / Choi, Jung Kyu; Lee, Areum; Kim, Seyoung; Ham, Sihyun; No, Kwanghyun; Kim, Jong Seung.

In: Organic Letters, Vol. 8, No. 8, 13.04.2006, p. 1601-1604.

Research output: Contribution to journalArticle

Choi, Jung Kyu ; Lee, Areum ; Kim, Seyoung ; Ham, Sihyun ; No, Kwanghyun ; Kim, Jong Seung. / Fluorescent ratiometry of tetrahomodioxacalix[4]arene pyrenylamides upon cation complexation. In: Organic Letters. 2006 ; Vol. 8, No. 8. pp. 1601-1604.
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