Free-standing nanocomposite multilayers with various length scales, adjustable internal structures, and functionalities

Seryun Lee, Bokyoung Lee, Bumjoon J. Kim, Junwoo Park, Misang Yoo, Wan Ki Bae, Kookheon Char, Craig J. Hawker, Joona Bang, Jinhan Cho

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

We introduce an innovative and robust method for the preparation of nanocomposite multilayers, which allows accurate control over the placement of functional groups as well as the composition and dimensions of individual layers/internal structure. By employing the photocross-linkable polystyrene (PS-N 3, M n = 28.0 kg/mol) with 10 wt % azide groups (-N 3) for host polymer and/or the PS-N 3-SH (M n = 6.5 kg/mol) with azide and thiol (-SH) groups for capping ligands of inorganic nanoparticles, nanocomposite multilayers were prepared by an efficient photocross-linking layer-by-layer process, without perturbing underlying layers and nanostructures. The thickness of individual layers could be controlled from a few to hundreds of nanometers producing highly ordered internal structure, and the resulting nanocomposite multilayers, consisting of polymer and inorganic nanoparticles (CdSe@ZnS, Au, and Pt), exhibit a variety of interesting physical properties. These include prolonged photoluminescent durability, facile color tuning, and the ability to prepare functional free-standing films that can have the one-dimensional photonic band gap and furthermore be patterned by photolithography. This robust and tailored method opens a new route for the design of functional film devices based on nanocomposite multilayers.

Original languageEnglish
Pages (from-to)2579-2587
Number of pages9
JournalJournal of the American Chemical Society
Volume131
Issue number7
DOIs
Publication statusPublished - 2009 Feb 25

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Nanocomposites
Multilayers
Azides
Nanoparticles
Polymers
Optics and Photonics
Photonic band gap
Nanostructures
Polystyrenes
Photolithography
Sulfhydryl Compounds
Functional groups
Durability
Color
Tuning
Physical properties
Ligands
Equipment and Supplies
Chemical analysis

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Free-standing nanocomposite multilayers with various length scales, adjustable internal structures, and functionalities. / Lee, Seryun; Lee, Bokyoung; Kim, Bumjoon J.; Park, Junwoo; Yoo, Misang; Bae, Wan Ki; Char, Kookheon; Hawker, Craig J.; Bang, Joona; Cho, Jinhan.

In: Journal of the American Chemical Society, Vol. 131, No. 7, 25.02.2009, p. 2579-2587.

Research output: Contribution to journalArticle

Lee, Seryun ; Lee, Bokyoung ; Kim, Bumjoon J. ; Park, Junwoo ; Yoo, Misang ; Bae, Wan Ki ; Char, Kookheon ; Hawker, Craig J. ; Bang, Joona ; Cho, Jinhan. / Free-standing nanocomposite multilayers with various length scales, adjustable internal structures, and functionalities. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 7. pp. 2579-2587.
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