From ferronickel slag to value-added refractory materials: A microwave sintering strategy

Zhiwei Peng, Huimin Tang, Robin Augustine, Joonho Lee, Weiguang Tian, Yanhu Chen, Foquan Gu, Yuanbo Zhang, Guanghui Li, Tao Jiang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The present study proposes a novel strategy for preparation of refractory materials from potentially hazardous ferronickel slag by microwave sintering of the slag with addition of sintered magnesia in which a series of chemical reactions were involved. This strategy was developed based on examination of the phase transformations and microstructural changes of the slag during microwave sintering through X-ray diffraction (XRD) analysis and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) analysis, which determined the properties of refractory materials derived from the slag. It was shown that under microwave irradiation there existed rapid transformation of the olivine phase in the slag to high-melting point phases, including forsterite and spinels (e.g., magnesium iron chromate spinel, magnesium chromate spinel, and magnesium iron aluminate spinel). As a result, a high-quality refractory material with refractoriness of 1730 °C, bulk density of 2.80 g/cm3, apparent porosity of 1.6%, and compressive strength of 206.62 MPa was obtained by microwave sintering of the slag at 1350 °C for only 20 min with addition of 25 wt % sintered magnesia. Because the microwave sintering strategy not only elevated the refractoriness by 70 °C, but also reduced the heating duration required by the conventional approach by 6 times, it demonstrated apparent technological superiority and wide application prospect in preparing superior-quality refractory materials from ferronickel slag and relevant industrial waste, which contributed to conservation of resources and energy as well as environmental protection.

Original languageEnglish
Pages (from-to)521-531
Number of pages11
JournalResources, Conservation and Recycling
Volume149
DOIs
Publication statusPublished - 2019 Oct 1

Fingerprint

slag
magnesium
chromate
spinel
hercynite
forsterite
sintering
material
microwave
Value added
Microwave
industrial waste
compressive strength
chemical reaction
X-ray spectroscopy
bulk density
energy
olivine
environmental protection
irradiation

Keywords

  • Ferronickel slag
  • Microwave sintering
  • Phase transformation
  • Refractory material
  • Spinel

ASJC Scopus subject areas

  • Waste Management and Disposal
  • Economics and Econometrics

Cite this

From ferronickel slag to value-added refractory materials : A microwave sintering strategy. / Peng, Zhiwei; Tang, Huimin; Augustine, Robin; Lee, Joonho; Tian, Weiguang; Chen, Yanhu; Gu, Foquan; Zhang, Yuanbo; Li, Guanghui; Jiang, Tao.

In: Resources, Conservation and Recycling, Vol. 149, 01.10.2019, p. 521-531.

Research output: Contribution to journalArticle

Peng, Zhiwei ; Tang, Huimin ; Augustine, Robin ; Lee, Joonho ; Tian, Weiguang ; Chen, Yanhu ; Gu, Foquan ; Zhang, Yuanbo ; Li, Guanghui ; Jiang, Tao. / From ferronickel slag to value-added refractory materials : A microwave sintering strategy. In: Resources, Conservation and Recycling. 2019 ; Vol. 149. pp. 521-531.
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AU - Tian, Weiguang

AU - Chen, Yanhu

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AU - Zhang, Yuanbo

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AB - The present study proposes a novel strategy for preparation of refractory materials from potentially hazardous ferronickel slag by microwave sintering of the slag with addition of sintered magnesia in which a series of chemical reactions were involved. This strategy was developed based on examination of the phase transformations and microstructural changes of the slag during microwave sintering through X-ray diffraction (XRD) analysis and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) analysis, which determined the properties of refractory materials derived from the slag. It was shown that under microwave irradiation there existed rapid transformation of the olivine phase in the slag to high-melting point phases, including forsterite and spinels (e.g., magnesium iron chromate spinel, magnesium chromate spinel, and magnesium iron aluminate spinel). As a result, a high-quality refractory material with refractoriness of 1730 °C, bulk density of 2.80 g/cm3, apparent porosity of 1.6%, and compressive strength of 206.62 MPa was obtained by microwave sintering of the slag at 1350 °C for only 20 min with addition of 25 wt % sintered magnesia. Because the microwave sintering strategy not only elevated the refractoriness by 70 °C, but also reduced the heating duration required by the conventional approach by 6 times, it demonstrated apparent technological superiority and wide application prospect in preparing superior-quality refractory materials from ferronickel slag and relevant industrial waste, which contributed to conservation of resources and energy as well as environmental protection.

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