FT-IR and isotherm study on anion adsorption onto novel chelating fibers

Young Gun Ko; Ung Su Choi; Tai Young Kim; Dong June Ahn; Yong Jin Chun

doi:10.1002/1521-3927(20020601)23:9<535::AID-MARC535>3.0.CO;2-S

FT-IR and isotherm study on anion adsorption onto novel chelating fibers

Young Gun Ko, Ung Su Choi, Tai Young Kim, Dong June Ahn, Yong Jin Chun

KU-KIST Graduate School of Converging Science and Technology

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

A new chelating fiber, poly(acrylo-amidino diethylenediamine, was synthesized based on polyacrylonitrile fibers in diethylenetriamine with the aid of AlCl₃. Complex formation with CrO₄² was strongly pH dependent as complexes formed only in the presence of NH₃⁺ and NH₂⁺. In the medium pH region, both ionic and hydrogen bonds were formed between poly(acrylo-amidino diethylenediamine) and the chromate ion, as was confirmed by means of FT-IR spectroscopy.

Original language	English
Pages (from-to)	535-539
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	23
Issue number	9
DOIs	https://doi.org/10.1002/1521-3927(20020601)23:9<535::AID-MARC535>3.0.CO;2-S
Publication status	Published - 2002 Jun 28

Keywords

Chelating fiber
FT-IR
Ion exchangers
PH selectivity
Polymer/chromate ion complex

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/1521-3927(20020601)23:9<535::AID-MARC535>3.0.CO;2-S

Cite this

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title = "FT-IR and isotherm study on anion adsorption onto novel chelating fibers",

abstract = "A new chelating fiber, poly(acrylo-amidino diethylenediamine, was synthesized based on polyacrylonitrile fibers in diethylenetriamine with the aid of AlCl3. Complex formation with CrO42 was strongly pH dependent as complexes formed only in the presence of NH3+ and NH2+. In the medium pH region, both ionic and hydrogen bonds were formed between poly(acrylo-amidino diethylenediamine) and the chromate ion, as was confirmed by means of FT-IR spectroscopy.",

keywords = "Chelating fiber, FT-IR, Ion exchangers, PH selectivity, Polymer/chromate ion complex",

author = "Ko, {Young Gun} and Choi, {Ung Su} and Kim, {Tai Young} and Ahn, {Dong June} and Chun, {Yong Jin}",

year = "2002",

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doi = "10.1002/1521-3927(20020601)23:9<535::AID-MARC535>3.0.CO;2-S",

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T1 - FT-IR and isotherm study on anion adsorption onto novel chelating fibers

AU - Ko, Young Gun

AU - Choi, Ung Su

AU - Kim, Tai Young

AU - Ahn, Dong June

AU - Chun, Yong Jin

PY - 2002/6/28

Y1 - 2002/6/28

N2 - A new chelating fiber, poly(acrylo-amidino diethylenediamine, was synthesized based on polyacrylonitrile fibers in diethylenetriamine with the aid of AlCl3. Complex formation with CrO42 was strongly pH dependent as complexes formed only in the presence of NH3+ and NH2+. In the medium pH region, both ionic and hydrogen bonds were formed between poly(acrylo-amidino diethylenediamine) and the chromate ion, as was confirmed by means of FT-IR spectroscopy.

AB - A new chelating fiber, poly(acrylo-amidino diethylenediamine, was synthesized based on polyacrylonitrile fibers in diethylenetriamine with the aid of AlCl3. Complex formation with CrO42 was strongly pH dependent as complexes formed only in the presence of NH3+ and NH2+. In the medium pH region, both ionic and hydrogen bonds were formed between poly(acrylo-amidino diethylenediamine) and the chromate ion, as was confirmed by means of FT-IR spectroscopy.

KW - Chelating fiber

KW - FT-IR

KW - Ion exchangers

KW - PH selectivity

KW - Polymer/chromate ion complex

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FT-IR and isotherm study on anion adsorption onto novel chelating fibers

Abstract

Keywords

ASJC Scopus subject areas

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