Fully biobased robust biocomposites of PLA with assisted nucleation by monodispersed stereocomplexed polylactide particles

Gulnaz BiBi, Yongmee Jung, Jongchoo Lim, Soo Hyun Kim

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Fully biodegradable biocomposites are a desirable choice among the synthetic plastics due to their increasing adverse ecological issues. Stereocomplexed polylactide submicronparticles (s-PLA SP), which provide dense nucleating sites to PLLA in the crystallization process, were used to prepare homogenous PLLA biocomposites to enhance the thermal and mechanical properties of PLLA. Herein, we report the synthesis of monodispersed s-PLA SP and preparation of biocomposites of PLLA incorporating s-PLA SP. The synthetic system for s-PLA SP is comprised of two steps. The first step involves solvating PLLA and PDLA in respective reactors. The second step is the stereocomplexation of the dissolved polymer in the mixing reactor. The polymer solvation conditions greatly affect the s-PLA particle size and distribution. Therefore, we studied the variation of s-PLA particle size and polydispersity index (PDI) due to the effect of the polymer solvation parameters, such as homopolymer concentration, solvation time, temperature, pressure and molecular weight, as the first step. The optimum conditions established were 50 °C, 300 b, with 5% homopolymer solvation for 12 h. In the second step, s-PLA SP formation was carried out at the previously established reaction conditions of 70 °C, 250 b for 2 h. The PLA homopolymers (Mn ∼ 57 kg mol-1) produced s-PLA SP smaller than 963 nm with a PDI of 0.12, as analyzed by DLS and SEM at the optimum reaction conditions. We cast completely biobased homocomposites (BC) for high performance by homogeneously dispersing s-PLA SP in the high molecular weight PLLA matrix (Mn ∼ 200 kg mol-1) in chloroform, followed by annealing. The solution casting DSC results show the enhanced crystallization of PLLA for various compositions of BC ranging from 0.5% to 5%. An increase in the concentration of s-PLA SP increases the thermal and mechanical properties of the PLA BC. Effective nucleation with decreased spherulite size was noticed for the 5% BC with 963 nm s-PLA SP incorporated into the casting solution, as inferred by SEM analysis. The tensile strength and Young's modulus increased from 29 MPa to 73 MPa and 1.3 GPa to 3.2 GPa, respectively, whereas the Xcc increased from 20% to 35% and Tcc increased from 98 °C to 113 °C with the 5% composition involving 963 nm s-PLA SP.

Original languageEnglish
Pages (from-to)111129-111138
Number of pages10
JournalRSC Advances
Volume6
Issue number112
DOIs
Publication statusPublished - 2016

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Solvation
Nucleation
Homopolymerization
Polydispersity
Casting
Polymers
Thermodynamic properties
Crystallization
Molecular weight
Particle size
Mechanical properties
Scanning electron microscopy
Chlorine compounds
Chemical analysis
Tensile strength
Elastic moduli
Annealing
Plastics
poly(lactide)
Chloroform

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Fully biobased robust biocomposites of PLA with assisted nucleation by monodispersed stereocomplexed polylactide particles. / BiBi, Gulnaz; Jung, Yongmee; Lim, Jongchoo; Kim, Soo Hyun.

In: RSC Advances, Vol. 6, No. 112, 2016, p. 111129-111138.

Research output: Contribution to journalArticle

BiBi, Gulnaz ; Jung, Yongmee ; Lim, Jongchoo ; Kim, Soo Hyun. / Fully biobased robust biocomposites of PLA with assisted nucleation by monodispersed stereocomplexed polylactide particles. In: RSC Advances. 2016 ; Vol. 6, No. 112. pp. 111129-111138.
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abstract = "Fully biodegradable biocomposites are a desirable choice among the synthetic plastics due to their increasing adverse ecological issues. Stereocomplexed polylactide submicronparticles (s-PLA SP), which provide dense nucleating sites to PLLA in the crystallization process, were used to prepare homogenous PLLA biocomposites to enhance the thermal and mechanical properties of PLLA. Herein, we report the synthesis of monodispersed s-PLA SP and preparation of biocomposites of PLLA incorporating s-PLA SP. The synthetic system for s-PLA SP is comprised of two steps. The first step involves solvating PLLA and PDLA in respective reactors. The second step is the stereocomplexation of the dissolved polymer in the mixing reactor. The polymer solvation conditions greatly affect the s-PLA particle size and distribution. Therefore, we studied the variation of s-PLA particle size and polydispersity index (PDI) due to the effect of the polymer solvation parameters, such as homopolymer concentration, solvation time, temperature, pressure and molecular weight, as the first step. The optimum conditions established were 50 °C, 300 b, with 5{\%} homopolymer solvation for 12 h. In the second step, s-PLA SP formation was carried out at the previously established reaction conditions of 70 °C, 250 b for 2 h. The PLA homopolymers (Mn ∼ 57 kg mol-1) produced s-PLA SP smaller than 963 nm with a PDI of 0.12, as analyzed by DLS and SEM at the optimum reaction conditions. We cast completely biobased homocomposites (BC) for high performance by homogeneously dispersing s-PLA SP in the high molecular weight PLLA matrix (Mn ∼ 200 kg mol-1) in chloroform, followed by annealing. The solution casting DSC results show the enhanced crystallization of PLLA for various compositions of BC ranging from 0.5{\%} to 5{\%}. An increase in the concentration of s-PLA SP increases the thermal and mechanical properties of the PLA BC. Effective nucleation with decreased spherulite size was noticed for the 5{\%} BC with 963 nm s-PLA SP incorporated into the casting solution, as inferred by SEM analysis. The tensile strength and Young's modulus increased from 29 MPa to 73 MPa and 1.3 GPa to 3.2 GPa, respectively, whereas the Xcc increased from 20{\%} to 35{\%} and Tcc increased from 98 °C to 113 °C with the 5{\%} composition involving 963 nm s-PLA SP.",
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